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CAS No.: | 7631-99-4 |
---|---|
Name: | Sodium nitrate |
Article Data: | 585 |
Molecular Structure: | |
Formula: | NaNO3 |
Molecular Weight: | 84.9947 |
Synonyms: | Cubic niter;Sodium saltpeter;Sodium Nitrate ACS Crystals;Saltpeter (Chile) (VAN);Chile saltpeter;NiterSee;Nitrate of soda;Sodium nitrate(DOT);Soda niter;Nitrate de sodium;Nitric acid, sodium salt;Niter (VAN);Nitric acid sodium salt;Sodium(I) nitrate (1:1);Nitrate, sodium;etabisulfite;Sodium Nitrate for Industrial use;Industrial Sodium Nitrate;Saltpeter (Chile);Nitric acid monosodium salt;Nitrate de sodium [French];Nitric acid ammonium salt; |
EINECS: | 231-554-3 |
Density: | 2.257 g/cm3 |
Melting Point: | 306 °C |
Boiling Point: | 83 °C at 760 mmHg |
Solubility: | 900 g/L (20 °C) in water |
Appearance: | white crystalline solid |
Hazard Symbols: | O,Xn,Xi,C |
Risk Codes: | 8-22-36/37/38-36/38-34 |
Safety: | 17-26-27-36/37/39-37/39-36-45 |
Transport Information: | UN 1498 5.1/PG 3 |
PSA: | 68.88000 |
LogP: | 0.28410 |
Ce(OCMe3)(NO3)3(THF)2
sodium t-butanolate
A
sodium nitrate
B
Ce(OCMe3)4(THF)2
Conditions | Yield |
---|---|
In tetrahydrofuran exclusion of air and water, stirred for 20 h, 3 equiv. of NaOCMe3; centrifuged, removal of solvent; | A 100% B 80-95 |
Conditions | Yield |
---|---|
In water byproducts: oxalic acid; between 15 and 65°C;; pure NaNO3;; | 99% |
ammonium cerium (IV) nitrate
sodium t-butanolate
A
sodium nitrate
B
Ce(OCMe3)(NO3)3(THF)2
C
tert-butyl alcohol
Conditions | Yield |
---|---|
In tetrahydrofuran byproducts: NH3; exclusion of air and water, stirred for 2 h; filtered (NaNO3), removal of solvent from filtrate, extn. (toluene), removal of solvent; elem. anal.; | A 99% B 56% C n/a |
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: NOCl; at ambient pressure; treatment of solid NaCl with a Cl2/NO2-mixture; 98.8% NaNO3 after 8-10times;; | 98.8% |
In neat (no solvent) byproducts: NOCl; at ambient pressure; treatment of solid NaCl with a Cl2/NO2-mixture; 98.8% NaNO3 after 8-10times;; | 98.8% |
In neat (no solvent) byproducts: NOCl; treatment of solid NaCl with NO2;; dissolving NaNO3 in liquid NH3, separation from unreacted chloride;; |
ammonium cerium (IV) nitrate
sodium t-butanolate
A
sodium nitrate
B
Ce2(OCMe3)4(μ-OCMe3)3(μ3-OCMe3)2Na
C
tert-butyl alcohol
Conditions | Yield |
---|---|
In tetrahydrofuran byproducts: NH3; exclusion of air and water, stirred for 2 h; filtered (NaNO3), removal of solvent from filtrate, extn. (hexane), removal of solvent; elem. anal.; | A 94% B 96% C n/a |
ammonium cerium (IV) nitrate
sodium t-butanolate
A
sodium nitrate
B
Ce(OCMe3)4(THF)2
C
tert-butyl alcohol
Conditions | Yield |
---|---|
In tetrahydrofuran byproducts: NH3; exclusion of air and water, stirred for 2 h; filtered (NaNO3), removal of solvent from filtrate, extn. (hexane), removal of solvent; elem. anal.; | A 96% B 65% C n/a |
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide N2O4 addn. (dropwise) to NaNO2 suspn. (DMF), soln. keeping for 1 h at 0°C, oxides of nitrogen removal (vac.), pptn. on ether addn.; | 81% |
chlorine nitrate
sodium chloride
A
hydrogenchloride
B
sodium nitrate
C
hypochloric acid
D
chlorine
Conditions | Yield |
---|---|
In neat (no solvent) experiments performed in a glass Knudsen cell at 298 K; not isolated, detected by mass spectrometry; | A 0% B n/a C n/a D 81% |
chlorine nitrate
A
hydrogenchloride
B
sodium nitrate
C
hypochloric acid
D
chlorine
Conditions | Yield |
---|---|
With synthetic sea salt In neat (no solvent) experiments performed in a glass Knudsen cell at 298 K; not isolated, detected by mass spectrometry; | A n/a B n/a C n/a D 78% |
Conditions | Yield |
---|---|
In nitric acid 2-3 times washed with H2O; dried at 60-70°C;; | A n/a B 70% |
Sodium nitrate,with the CAS registry number 7631-99-4, it is also named as Nitric acid monosodium salt. The product's categories are Inorganics; Water Ttreatment Chemicals; ICP CRMs Spectroscopy; ICP-OES/-MS; ICP Spectroscopy; Matrix Selection; Nitrate Alphabetic; S; SN - SZ; Anionic Solutions Chromatography; Anionic Standard Solutions Alphabetic; Ion Chromatography; Application CRMs; N; NA - NI, and the other registry number is 862599-22-2. Besides, it is white crystalline solid, which should be stored in a cool, ventilated warehouse. In addition, its molecular formula is NaNO3 and molecular weight is 84.99.
Physical properties about Sodium nitrate are: (1)ACD/LogP: -0.129; (2)ACD/LogD (pH 5.5): -0.13; (3)ACD/LogD (pH 7.4): -0.13; (4)ACD/BCF (pH 5.5): 1.00; (5)ACD/BCF (pH 7.4): 1.00; (6)#H bond acceptors: 4; (7)#H bond donors: 1; (8)Enthalpy of Vaporization: 37.72 kJ/mol; (9)Boiling Point: 83 °C at 760 mmHg; (10)Vapour Pressure: 49.8 mmHg at 25°C
Preparation of Sodium nitrate: this chemical can be prepared by the reaction of NaCl or soda ash with Nitric acid.
NaCl + HNO3 → NaNO3 + HCl
Na2CO3 + 2HNO3 → 2NaNO3 + H2O + CO2
Uses of Sodium nitrate: this chemical is used as a fertilizer and a raw material for the manufacture of gunpowder. It is also used to make a resin by combining with iron hydroxide. Furthermore, it can be combined with Sulfuric acid to produce nitric acid. And it can be used as a substitute oxidizer used in fireworks as a replacement for potassium nitrate. It is used for heat transfer in solar power plants and heat storage. What's more, it can be used for facultative microorganism respiration in the wastewater industry.
When you are using this chemical, please be cautious about it as the following: it may cause fire in contact with combustible material. Please keep away from combustible material. It is also harmful if swallowed. And it is irritating to eyes, respiratory system and skin. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Moreover, you should wear suitable protective clothing, gloves and eye/face protection. And please take off immediately all contaminated clothing. Additionally, in case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
People can use the following data to convert to the molecule structure.
(1)SMILES: [Na+].[O-][N+]([O-])=O;
(2)InChI: InChI=1/NO3.Na/c2-1(3)4;/q-1;+1;
(3)InChIKey: VWDWKYIASSYTQR-UHFFFAOYAL;
The toxicity data is as follows:
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
child | LDLo | oral | 22500ug/kg (22.5mg/kg) | BLOOD: METHEMOGLOBINEMIA-CARBOXYHEMOGLOBIN | Journal of Toxicology, Clinical Toxicology. Vol. 32, Pg. 173, 1994. |
mouse | LD50 | intravenous | 175mg/kg (175mg/kg) | Archiv fuer Toxikologie. Vol. 21, Pg. 89, 1965. | |
rabbit | LD50 | oral | 2680mg/kg (2680mg/kg) | Southwestern Veterinarian. Vol. 27, Pg. 246, 1974. | |
rat | LD | intraperitoneal | > 181mg/kg (181mg/kg) | Toxicology and Applied Pharmacology. Vol. 5, Pg. 750, 1963. | |
rat | LD50 | oral | 1267mg/kg (1267mg/kg) | Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 46(12), Pg. 66, 1981. | |
women | TDLo | oral | 14mg/kg (14mg/kg) | CARDIAC: PULSE RATE INCREASE WITHOUT FALL IN BP LUNGS, THORAX, OR RESPIRATION: CYANOSIS BLOOD: METHEMOGLOBINEMIA-CARBOXYHEMOGLOBIN | Journal of Toxicology, Clinical Toxicology. Vol. 32, Pg. 173, 1994. |