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7631-99-4

Basic Information
CAS No.: 7631-99-4
Name: Sodium nitrate
Molecular Structure:
Molecular Structure of 7631-99-4 (Sodium nitrate)
Formula: NaNO3
Molecular Weight: 84.99
Synonyms: Cubic niter;Sodium saltpeter;Sodium Nitrate ACS Crystals;Saltpeter (Chile) (VAN);Chile saltpeter;NiterSee;Nitrate of soda;Sodium nitrate(DOT);Soda niter;Nitrate de sodium;Nitric acid, sodium salt;Niter (VAN);Nitric acid sodium salt;Sodium(I) nitrate (1:1);Nitrate, sodium;etabisulfite;Sodium Nitrate for Industrial use;Industrial Sodium Nitrate;Saltpeter (Chile);Nitric acid monosodium salt;Nitrate de sodium [French];Nitric acid ammonium salt;
EINECS: 231-554-3
Density: 2.257 g/cm3
Melting Point: 306 °C
Boiling Point: 83 °C at 760 mmHg
Flash Point:
Solubility: 900 g/L (20 °C) in water
Appearance: white crystalline solid
Hazard Symbols: OxidizingO,HarmfulXn,IrritantXi,CorrosiveC
Risk Codes: 8-22-36/37/38-36/38-34
Safety: 17-26-27-36/37/39-37/39-36-45
Transport Information: UN 1498 5.1/PG 3
PSA: 68.88000
LogP: 0.28410
Synthetic route
121314-35-0

Ce(OCMe3)(NO3)3(THF)2

865-48-5

sodium t-butanolate

A

7631-99-4

sodium nitrate

B

122423-58-9

Ce(OCMe3)4(THF)2

Conditions
ConditionsYield
In tetrahydrofuran exclusion of air and water, stirred for 20 h, 3 equiv. of NaOCMe3; centrifuged, removal of solvent;A 100%
B 80-95
7697-37-2

nitric acid

62-76-0

sodium oxalate

7631-99-4

sodium nitrate

Conditions
ConditionsYield
In water byproducts: oxalic acid; between 15 and 65°C;; pure NaNO3;;99%
16774-21-3

ammonium cerium (IV) nitrate

865-48-5

sodium t-butanolate

A

7631-99-4

sodium nitrate

B

121314-35-0

Ce(OCMe3)(NO3)3(THF)2

C

75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
In tetrahydrofuran byproducts: NH3; exclusion of air and water, stirred for 2 h; filtered (NaNO3), removal of solvent from filtrate, extn. (toluene), removal of solvent; elem. anal.;A 99%
B 56%
C n/a
10102-44-0

Nitrogen dioxide

7647-14-5

sodium chloride

7631-99-4

sodium nitrate

Conditions
ConditionsYield
In neat (no solvent) byproducts: NOCl; at ambient pressure; treatment of solid NaCl with a Cl2/NO2-mixture; 98.8% NaNO3 after 8-10times;;98.8%
In neat (no solvent) byproducts: NOCl; at ambient pressure; treatment of solid NaCl with a Cl2/NO2-mixture; 98.8% NaNO3 after 8-10times;;98.8%
In neat (no solvent) byproducts: NOCl; treatment of solid NaCl with NO2;; dissolving NaNO3 in liquid NH3, separation from unreacted chloride;;
16774-21-3

ammonium cerium (IV) nitrate

865-48-5

sodium t-butanolate

A

7631-99-4

sodium nitrate

B

122423-62-5

Ce2(OCMe3)4(μ-OCMe3)3(μ3-OCMe3)2Na

C

75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
In tetrahydrofuran byproducts: NH3; exclusion of air and water, stirred for 2 h; filtered (NaNO3), removal of solvent from filtrate, extn. (hexane), removal of solvent; elem. anal.;A 94%
B 96%
C n/a
16774-21-3

ammonium cerium (IV) nitrate

865-48-5

sodium t-butanolate

A

7631-99-4

sodium nitrate

B

122423-58-9

Ce(OCMe3)4(THF)2

C

75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
In tetrahydrofuran byproducts: NH3; exclusion of air and water, stirred for 2 h; filtered (NaNO3), removal of solvent from filtrate, extn. (hexane), removal of solvent; elem. anal.;A 96%
B 65%
C n/a

sodium nitrite

sodium nitrite

7631-99-4

sodium nitrate

Conditions
ConditionsYield
In N,N-dimethyl-formamide N2O4 addn. (dropwise) to NaNO2 suspn. (DMF), soln. keeping for 1 h at 0°C, oxides of nitrogen removal (vac.), pptn. on ether addn.;81%
14545-72-3

chlorine nitrate

7647-14-5

sodium chloride

A

7647-01-0

hydrogenchloride

B

7631-99-4

sodium nitrate

C

14989-30-1

hypochloric acid

D

7782-50-5

chlorine

Conditions
ConditionsYield
In neat (no solvent) experiments performed in a glass Knudsen cell at 298 K; not isolated, detected by mass spectrometry;A 0%
B n/a
C n/a
D 81%
14545-72-3

chlorine nitrate

A

7647-01-0

hydrogenchloride

B

7631-99-4

sodium nitrate

C

14989-30-1

hypochloric acid

D

7782-50-5

chlorine

Conditions
ConditionsYield
With synthetic sea salt In neat (no solvent) experiments performed in a glass Knudsen cell at 298 K; not isolated, detected by mass spectrometry;A n/a
B n/a
C n/a
D 78%

sodium bromide dihydrate

mercury(II) oxide

A

7631-99-4

sodium nitrate

B

mercury dibromide

Conditions
ConditionsYield
In nitric acid 2-3 times washed with H2O; dried at 60-70°C;;A n/a
B 70%
13477-34-4

calcium(II) nitrate

7647-14-5

sodium chloride

7631-99-4

sodium nitrate

Conditions
ConditionsYield
In water preparation on cation exchange resins, 52% Ca-nitrate soln., 26% NaCl-soln.;; crystn.;;70%
In water preparation on cation exchange resins, 52% Ca-nitrate soln., 26% NaCl-soln.;; crystn.;;70%
In water equilibrium in aq. soln.;;

sodium azide

Nitryl chloride

A

7631-99-4

sodium nitrate

B

7647-14-5

sodium chloride

Conditions
ConditionsYield
In neat (no solvent) ambient temp.;A 55%
B 12%
In neat (no solvent) ambient temp.;A 55%
B 12%
7697-37-2

nitric acid

497-19-8

sodium carbonate

7631-99-4

sodium nitrate

Conditions
ConditionsYield
at 90℃; under 760.051 Torr; for 0.3h; Concentration; Temperature; Time;45%
In water react. of natural soda with dild. HNO3, tereatment of the Na2CO3-containing mineral with the soln. at 200°C under pressure, filtration, evapn., fractionated crystn.;; NaNO3 and mixture of K- and Na-nitrate after fractionated crystn.;;
With leucite In water treatment of leucite with HNO3, react. of resulting nitrates with Na2CO3;;

lanthanum(III) nitrate hexahydrate

23040-18-8

2-(diphenylphosphinoyl)-2-phenylethenol

7440-23-5

sodium

A

7631-99-4

sodium nitrate

B

tris[2-(diphenylphosphonoyl)-2-phenylethenolato]lanthanum(III) 1.5hydrate

Conditions
ConditionsYield
In tetrahydrofuran addn. of Na to soln. of P-ligand, addn. of soln. of lanthanide nitrate, stirring (10 - 60 min; pptn. of NaNO3); addn. of water, solvent removal (vac.), washing (water), dissol. in Et2O, filtration, solvent removal;A n/a
B 43%

iodo-methanesulfonic acid ; sodium salt

silver nitrate

A

7631-99-4

sodium nitrate

B

36647-97-9

iodomethanesulfonic acid; silver salt

Conditions
ConditionsYield
In ethanol solns. AgNO3 in hot EtOH and ICH2SO3Na*H2O in hot EtOH were mixed and allowed to cool to room temp.; soln. was filtered and concd.; elem. anal.;A n/a
B 31%
7664-93-9

sulfuric acid

7632-00-0

sodium nitrite

A

7631-99-4

sodium nitrate

B

10102-43-9

nitrogen(II) oxide

C

7757-82-6

sodium sulfate

D

10024-97-2

dinitrogen monoxide

Conditions
ConditionsYield
byproducts: H2O, N2; NO collection, storing over dil. sodium hydroxide soln. (NO2 impurity elimination);A n/a
B n/a
C n/a
D 1%

silver nitrate

7647-14-5

sodium chloride

A

7631-99-4

sodium nitrate

B

silver(I) chloride

Conditions
ConditionsYield
In water Product distribution / selectivity;
With benzalkonium chloride (BC) In water Product distribution / selectivity;
13446-18-9

magnesium(II) nitrate

ammonium chloride

7647-14-5

sodium chloride

7631-99-4

sodium nitrate

Conditions
ConditionsYield
In water reaction in neutral aq. soln., pptn. of pure NaNO3 when cooling to 20 to 18°C;;
In water reaction in neutral aq. soln., pptn. of pure NaNO3 when cooling to 20 to 18°C;;

7697-37-2

nitric acid

497-19-8

sodium carbonate

7757-82-6

sodium sulfate

7631-99-4

sodium nitrate

Conditions
ConditionsYield
In water treatment of dolomite with HNO3, pptn. of CaSO4 and MgCO3 by successive addn. of Na2SO4 and Na2CO3, winning of NaNO3 from the filtrate;;
In water treatment of dolomite with HNO3, pptn. of CaSO4 and MgCO3 by successive addn. of Na2SO4 and Na2CO3, winning of NaNO3 from the filtrate;;

10102-44-0

Nitrogen dioxide

A

7631-99-4

sodium nitrate

B

7632-00-0

sodium nitrite

Conditions
ConditionsYield
oxidation;
oxidation;

sodium azide

16774-21-3

ammonium cerium (IV) nitrate

A

7631-99-4

sodium nitrate

B

ammonium nitrate

C

7727-37-9

nitrogen

D

Conditions
ConditionsYield
In water
In water
7631-99-4

sodium nitrate

nickel(II) chloride hexahydrate

1313-99-1

nickel(II) oxide

Conditions
ConditionsYield
In melt Kinetics; byproducts: NaCl, NO2, O2; mixt. of Na salt/Ni salt (8/1) heated up to 500°C with a rate of 150°C/h, cooled in furnace; washed with H2O, insol. residue filtered off; elem. anal.;100%
7631-99-4

sodium nitrate

copper(II) choride dihydrate

copper(II) oxide

Conditions
ConditionsYield
In melt byproducts: NaCl, NO2, O2; mixt. of Na salt/Cu salt (8/1) heated up to 500°C with a rate of 150°C/h, cooled in furnace; washed with H2O, insol. residue filtered off; elem. anal.;100%
7631-99-4

sodium nitrate

zinc nitrate tetrahydrate

zinc(II) oxide

Conditions
ConditionsYield
In melt Kinetics; byproducts: NaNO3, NO2, O2; mixt. of Na salt/Zn salt (8/1) heated up to 500°C with a rate of 150°C/h, cooled in furnace; washed with H2O, insol. residue filtered off; elem. anal.;100%
7631-99-4

sodium nitrate

7664-39-3

hydrogen fluoride

sodium fluoride

Conditions
ConditionsYield
20 min, 250 °C;;100%
20 min, 250 °C;;100%
7631-99-4

sodium nitrate

copper(II) nitrate trihydrate

copper(II) oxide

Conditions
ConditionsYield
In melt byproducts: NaNO3, NO2, O2; mixt. of Na salt/Cu salt (8/1) heated up to 500°C with a rate of 150°C/h, cooled in furnace; washed with H2O, insol. residue filtered off; elem. anal.;100%
7631-99-4

sodium nitrate

nickel(II) nitrate hexahydrate

1313-99-1

nickel(II) oxide

Conditions
ConditionsYield
In melt Kinetics; byproducts: NaNO3, NO2, O2; mixt. of Na salt/Ni salt (8/1) heated up to 500°C with a rate of 150°C/h, cooled in furnace; washed with H2O, insol. residue filtered off; elem. anal.;100%
7631-99-4

sodium nitrate

[(bpy)PdIV(CH2CMe2-o-C6H4)(F)(OTf)]

C20H20FN3O3Pd

Conditions
ConditionsYield
In acetonitrile at 25℃; for 5h;98%

tellurium

7631-99-4

sodium nitrate

tellurium(IV) oxide

tellurium(IV) oxide

Conditions
ConditionsYield
In melt Te and NaNO3 were molten for 2 h at 400-430 °C (molar ratio 1/2-2.5), the melt was dissolved in aq. KOH(10%) forming K2TeO3 which was treated with HNO3;;97.5%
67-56-1

methanol

7631-99-4

sodium nitrate

41754-63-6

Ni(6,6'-{[ethane-1,2-diylbis(azanylylidene)]bis(methanylylidene)}bis(2-methoxyphenolate))

C19H22N3NaNiO8

Conditions
ConditionsYield
In dichloromethane at 20℃; for 2h;97%
7631-99-4

sodium nitrate

barium sulfide

A

sodium sulfide

B

barium(II) nitrate

Conditions
ConditionsYield
With carbon disulfide; hydrogen sulfide In water metathesis of BaS with NaNO3 by react. of a mixt. of satd. solutions of NaNO3 and an excess of BaS in an atmosphere of H2S or in presence of C or H or CS2 or CO or hydrocarbons as other reducing agents; heating at 110 °C for 1 h;; isolation of Ba(NO3)2 and NaHS by fractional crystallization; reaction of NaHS forming Na2S and H2S; addition of a small amount of CS2 facilitates the isolation;;A 95%
B n/a
With carbon disulfide; hydrogen sulfide In water metathesis of BaS with NaNO3 by react. of a mixt. of satd. solutions of NaNO3 and an excess of BaS in an atmosphere of H2S or in presence of C or H or CS2 or CO or hydrocarbons as other reducing agents; heating at 110 °C for 1 h;; isolation of Ba(NO3)2 and NaHS by fractional crystallization; reaction of NaHS forming Na2S and H2S; addition of a small amount of CS2 facilitates the isolation;;A 95%
B n/a
7631-99-4

sodium nitrate

C12H18N2NiO2*H2O

2C12H18N2NiO2*2Na(1+)*2NO3(1-)

Conditions
ConditionsYield
In methanol; acetonitrile at 20℃; for 0.5h;95%
7631-99-4

sodium nitrate

7632-00-0

sodium nitrite

Conditions
ConditionsYield
With hydrogen; copper(II) oxide In neat (no solvent) byproducts: H2O; reaction in 30 min passing stream of H2 over NaNO3;;94.3%
With H2; copper(II) oxide In neat (no solvent) byproducts: H2O; reaction in 30 min passing stream of H2 over NaNO3;;94.3%
With iron addn. of NaOH;;86.4%
7631-99-4

sodium nitrate

222532-70-9

CH(O)C6H2(CH3)(CO)ORh(P(C6H5)3)2Cl

222532-69-6

CH(O)C6H2(CH3)(CO)ORh(P(C6H5)3)2O2NO

Conditions
ConditionsYield
In dichloromethane; water; acetone stirring (0.5 h), evapn.; filtering, washing (H2O), drying (vac.);94%
7631-99-4

sodium nitrate

13965-31-6

dichloro(2,2'-bipyridine)platinum(II)

4152-09-4

N-benzylethylenediamine

[Pt(bipyridine)(N-benzyl-1,2-ethanediamine)](NO3)2

Conditions
ConditionsYield
In water addn. of ethanediamine to aq. suspn. of Pt complex, stirring 2 h at 80°C; cooling, filtration, addn. of satd. aq. NaNO3, storage at roomtemp. overnight; crystals filtered off, washed with 0.05 M HNO3, dried; elem. anal.;93.2%
7631-99-4

sodium nitrate

(2-aminoethanethiolato-N,S)bis(ethylenediamine-N,N')cobalt(III) dinitrate

silver nitrate

[Ag[Co(en)2(2-aminoethanethiolato)]2](NO3)5 tetrahydrate

Conditions
ConditionsYield
In water addn. of soln. of AgNO3 (1 equiv.) in water to aq. soln. of (Co(en)2(SCH2CH2NH2))(NO3)2 (2 equiv.); stirring at room temp. for 30 min; addn. of aq. soln. of NaNO3; cooling in a refrigerator for 2 days, crystn., filtration, elem. anal.;93%

zinc perchlorate

7631-99-4

sodium nitrate

119142-71-1

6,16,2,5-tribenzena(1,4)-1,4,8,11,14,18,23,27-octaazabicyclo[9.9.9]nonacosaphane

[pCZn2(μ-ONO2)](ClO4)3

Conditions
ConditionsYield
Stage #1: zinc perchlorate; sodium nitrate In methanol at 20℃; for 0.5h;
Stage #2: 6,16,2,5-tribenzena(1,4)-1,4,8,11,14,18,23,27-octaazabicyclo[9.9.9]nonacosaphane In methanol at 20℃; for 12h;
93%
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    Sodium nitrate CAS No.:7631-99-4 hot sales

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    Sodium nitrate [Name] Sodium nitrate[7631-99-4] [Molecular formula] NaNO3 [Molecular weight] 84.99 Index Name Fused salt level Industrial Grade Puritys(as dry) 99.3% min 98.3% min

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    Sodium nitrate CAS: 7631-99-4

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    Sodium Nitrate Other names: Sodium Nitrate Tech grade, Sodium Nitrate industry grade, Nitrate of Soda, Soda Niter Cubic Nitre, Saliter Molecular formula: NaNO3 Cas No.: 7631-99-4 EINECS No.: 231-554-3 UN NO.: 1498 Hazard Class: 5.1 Ap

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  • Soda Niter CAS NO. 7631-99-4

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    Soda Niter CAS NO. 7631-99-4

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Specification

Sodium nitrate,with the CAS registry number 7631-99-4, it is also named as Nitric acid monosodium salt. The product's categories are Inorganics; Water Ttreatment Chemicals; ICP CRMs Spectroscopy; ICP-OES/-MS; ICP Spectroscopy; Matrix Selection; Nitrate Alphabetic; S; SN - SZ; Anionic Solutions Chromatography; Anionic Standard Solutions Alphabetic; Ion Chromatography; Application CRMs; N; NA - NI, and the other registry number is 862599-22-2. Besides, it is white crystalline solid, which should be stored in a cool, ventilated warehouse. In addition, its molecular formula is NaNO3 and molecular weight is 84.99.

Physical properties about Sodium nitrate are: (1)ACD/LogP: -0.129; (2)ACD/LogD (pH 5.5): -0.13; (3)ACD/LogD (pH 7.4): -0.13; (4)ACD/BCF (pH 5.5): 1.00; (5)ACD/BCF (pH 7.4): 1.00; (6)#H bond acceptors: 4; (7)#H bond donors: 1; (8)Enthalpy of Vaporization: 37.72 kJ/mol; (9)Boiling Point: 83 °C at 760 mmHg; (10)Vapour Pressure: 49.8 mmHg at 25°C

Preparation of Sodium nitrate: this chemical can be prepared by the reaction of NaCl or soda ash with Nitric acid.
NaCl + HNO3 → NaNO3 + HCl
Na2CO3 + 2HNO3 → 2NaNO3 + H2O + CO2

Uses of Sodium nitrate: this chemical is used as a fertilizer and a raw material for the manufacture of gunpowder. It is also used to make a resin by combining with iron hydroxide. Furthermore, it can be combined with Sulfuric acid to produce nitric acid. And it can be used as a substitute oxidizer used in fireworks as a replacement for potassium nitrate. It is used for heat transfer in solar power plants and heat storage. What's more, it can be used for facultative microorganism respiration in the wastewater industry.

When you are using this chemical, please be cautious about it as the following: it may cause fire in contact with combustible material. Please keep away from combustible material. It is also harmful if swallowed. And it is irritating to eyes, respiratory system and skin. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Moreover, you should wear suitable protective clothing, gloves and eye/face protection. And please take off immediately all contaminated clothing. Additionally, in case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)

People can use the following data to convert to the molecule structure.
(1)SMILES: [Na+].[O-][N+]([O-])=O;
(2)InChI: InChI=1/NO3.Na/c2-1(3)4;/q-1;+1;
(3)InChIKey: VWDWKYIASSYTQR-UHFFFAOYAL;

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
child LDLo oral 22500ug/kg (22.5mg/kg) BLOOD: METHEMOGLOBINEMIA-CARBOXYHEMOGLOBIN Journal of Toxicology, Clinical Toxicology. Vol. 32, Pg. 173, 1994.
mouse LD50 intravenous 175mg/kg (175mg/kg)   Archiv fuer Toxikologie. Vol. 21, Pg. 89, 1965.
rabbit LD50 oral 2680mg/kg (2680mg/kg)   Southwestern Veterinarian. Vol. 27, Pg. 246, 1974.
rat LD intraperitoneal > 181mg/kg (181mg/kg)   Toxicology and Applied Pharmacology. Vol. 5, Pg. 750, 1963.
rat LD50 oral 1267mg/kg (1267mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 46(12), Pg. 66, 1981.
women TDLo oral 14mg/kg (14mg/kg) CARDIAC: PULSE RATE INCREASE WITHOUT FALL IN BP

LUNGS, THORAX, OR RESPIRATION: CYANOSIS

BLOOD: METHEMOGLOBINEMIA-CARBOXYHEMOGLOBIN
Journal of Toxicology, Clinical Toxicology. Vol. 32, Pg. 173, 1994.