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Basic Information
| CAS No.: | 13863-41-7 | ||||
|---|---|---|---|---|---|
| Name: | Bromine chloride | ||||
| Article Data: | 99 | ||||
| Molecular Structure: | |||||
|
|
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| Formula: | BrCl | ||||
| Molecular Weight: | 115.357 | ||||
| Synonyms: | Brominechloride; Bromine monochloride; Bromochloride | ||||
| Density: | 2.172g/cm3 | ||||
| Melting Point: | -66℃ [HAW93] | ||||
| Boiling Point: | °Cat760mmHg | ||||
| Flash Point: | °C | ||||
| Solubility: | soluble H2O with ready hydrolysis, soluble carbon disulfide, ether [HAW93] | ||||
| Appearance: | colourless liquid with a fruity odour | ||||
| Hazard Symbols: |
 F, Xi
|
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| Risk Codes: | R11; R36/37/38 | ||||
| Safety: |
|
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| PSA: | 0.00000 | ||||
| LogP: | 1.53510 | ||||
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Synthetic route
Conditions
| Conditions | Yield |
|---|---|
| Kinetics; HOBr/He mixt. (by He bubbling through aq. HOBr soln. at 10-15°C) and Cl excess flowing into quartz flow tube reactor at 300 K and 2.5-3.03 mbar; mass spectrometric monitoring; | A 98% B 98% |
...Expand
- 65597-24-2
Chlorine(I) trifluoromethanesulfonate
- 13997-93-8
bromine(I) fluorosulfate
A
- 926-08-9
trifluoromethyl fluorosulfate
B
- 21595-44-8
trifluoromethyldisulfurylfluoride
C
- 13863-41-7
bromine chloride
Conditions
| Conditions | Yield |
|---|---|
| byproducts: Br2, Cl2; at room temp. for 12 h; | A n/a B 85% C n/a |
...Expand
Conditions
| Conditions | Yield |
|---|---|
| In neat (no solvent) Br2 and Cl2 were mixed in a ratio of 1:15 in a 20 l bulb; total pressure 960 mbar; mixture was allowed to equilibrate for 48 h; fluorescence spectroscopy; | 12.3% |
| at -30 - 30℃; Neat (no solvent); | |
| at -30 - 30℃; |
Conditions
| Conditions | Yield |
|---|---|
| Kinetics; HOBr/He mixt. passing over doped ice at 240 K sprayed onto flow tube wall; monitoring by TOF MS; | A n/a B n/a C 1% |
...Expand
- 15656-19-6
hypobromous acid
- 7647-14-5
sodium chloride
A
- 13863-41-7
bromine chloride
B
- 1310-73-2
sodium hydroxide
Conditions
| Conditions | Yield |
|---|---|
| In neat (no solvent) Kinetics; detected by MS; | |
| In neat (no solvent) Kinetics; |
...Expand
Conditions
| Conditions | Yield |
|---|---|
| Kinetics; |
...Expand
Conditions
| Conditions | Yield |
|---|---|
| With NaClO4 or HClO4 In water 25°C, pH 1, const. ionic strength (NaClO4 or HClO4), equilibration; monitoring by vapour pressure measurements and spectrophotometry; |
...Expand
- 56-23-5
tetrachloromethane
- 7726-95-6
bromine
A
- 127-18-4
1,1,2,2-tetrachloroethylene
B
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Bromotrichloromethane
C
- 594-18-3
dibromodichloromethane
D
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hexachloroethane
E
- 13863-41-7
bromine chloride
Conditions
| Conditions | Yield |
|---|---|
| In tetrachloromethane other Radiation; γ-radiation of Br2 soln. in CCl4 (free from air) at 25°C; mechanism discussed;; |
...Expand
- 56-23-5
tetrachloromethane
- 7726-95-6
bromine
A
- 75-62-7
Bromotrichloromethane
B
- 67-72-1
hexachloroethane
C
- 13863-41-7
bromine chloride
Conditions
| Conditions | Yield |
|---|---|
| In tetrachloromethane other Radiation; γ-radiation of Br2 soln. in CCl4 (free from air); yield depends on temp.;; |
...Expand
Conditions
| Conditions | Yield |
|---|---|
| Kinetics; Discharge-flow system, ClNO in excess, He as buffer gas, Br source: Br2 and H or O or Cl in He.; Monitored by resonance fluorescence.; |
...Expand
Raw Materials
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Bromine chloride
