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75-79-6

Basic Information
CAS No.: 75-79-6
Name: Methyltrichlorosilane
Molecular Structure:
Molecular Structure of 75-79-6 (Methyltrichlorosilane)
Formula: CH3Cl3Si
Molecular Weight: 149.48
Synonyms: KA13;LS 40;LS 40 (silane);Methylsilicon trichloride;Methylsilyl trichloride;Silane,trichloromethyl-;NSC 77069;TSL 8003;Trichloromethylsilane;Trichloromethylsilicon;
EINECS: 200-902-6
Density: 1.3 g/cm3
Melting Point: -77 °C
Boiling Point: 73.5 °C at 760 mmHg
Flash Point: -13 °C
Solubility: reacts with water
Appearance: colorless clear liquid
Hazard Symbols: FlammableF,IrritantXi
Risk Codes: 11-14-36/37/38
Safety: 26-39
Transport Information: UN 1250 3/PG 1
PSA: 0.00000
LogP: 2.27150
Synthetic route
4518-98-3

1,1,2,2-tetrachloro-1,2-dimethyldisilane

A

75-54-7

Dichloromethylsilane

B

75-79-6

Methyltrichlorosilane

Conditions
ConditionsYield
silica gel; 3,5-Dimethyl-1-<(2-triethoxysilyl)ethyl>-1H-pyrazol Product distribution; Mechanism; Heating; var. of catalyst, also with HCl;A 0.4%
B 99.6%
1558-25-4

(chloromethyl)trichlorosilane

789-25-3

HSiPh3

A

75-79-6

Methyltrichlorosilane

B

76-86-8

Triphenylsilyl chloride

Conditions
ConditionsYield
at 165 - 250℃; for 12h;A 87.3%
B 95.8%
at 165 - 210℃; for 12h;A 95.8%
B 87.3%
1558-25-4

(chloromethyl)trichlorosilane

776-76-1

methyldiphenylsilane

A

75-79-6

Methyltrichlorosilane

B

144-79-6

chloromethyldiphenylsilane

Conditions
ConditionsYield
at 125 - 210℃; for 12h;A 90.2%
B 95.6%
at 125 - 210℃; for 12h;A 95.6%
B 90.2%
4218-23-9

(trichloromethyl)methyldichlorosilane

75-78-5

dimethylsilicon dichloride

A

75-79-6

Methyltrichlorosilane

B

18171-30-7

(trichloromethyl)dimethylchlorosilane

Conditions
ConditionsYield
triphenylphosphine for 1h; Heating;A n/a
B 95%
56-23-5

tetrachloromethane

4518-98-3

1,1,2,2-tetrachloro-1,2-dimethyldisilane

A

75-79-6

Methyltrichlorosilane

B

4218-23-9

(trichloromethyl)methyldichlorosilane

Conditions
ConditionsYield
dichlorotris(triphenylphosphine)ruthenium(II) for 3h; Heating;A n/a
B 94%
triphenylphosphine for 2h; Heating;A 62%
B 62%
With triphenylphosphine at 80℃; for 2h;A n/a
B 62%
1558-24-3

trichloro(dichloromethyl)silane

776-76-1

methyldiphenylsilane

A

75-79-6

Methyltrichlorosilane

B

1558-25-4

(chloromethyl)trichlorosilane

C

144-79-6

chloromethyldiphenylsilane

Conditions
ConditionsYield
at 160 - 240℃; for 6h;A 15.6%
B 81.2%
C 93.1%
75-54-7

Dichloromethylsilane

107-05-1

3-chloroprop-1-ene

A

75-79-6

Methyltrichlorosilane

B

4518-94-9

dichloromethylpropylsilane

C

7787-93-1

dichloro(3-chloropropyl)methylsilane

Conditions
ConditionsYield
With hexachloroplatinic acid; tributyl-amine; acetic acid at 35 - 39℃; Autoclave; Inert atmosphere; Industrial scale;A 64 kg
B 70 kg
C 92.8%
at 65℃; for 12h;A 21.4%
B 16.6%
C 62%
platinum(IV) chloride In C12-olefin at 70 - 100℃; for 2h; Product distribution / selectivity;
bis(1,5-cyclooctadiene)diiridium(I) dichloride In chlorobenzene at 67.42 - 175.15℃; under 1500.15 - 1522.65 Torr; Product distribution / selectivity; Heating / reflux;
Stage #1: Dichloromethylsilane; 3-chloroprop-1-ene; platinum at -30 - 90℃; for 3h; Inert atmosphere;
Stage #2: With triphenylphosphine In toluene at 20℃; Product distribution / selectivity;
1558-25-4

(chloromethyl)trichlorosilane

766-77-8

Dimethylphenylsilane

A

75-79-6

Methyltrichlorosilane

B

768-33-2

phenyldimethylsilyl chloride

Conditions
ConditionsYield
at 125 - 210℃; for 2h;A 91.4%
B 88.6%
993-07-7

trimethylsilan

1558-25-4

(chloromethyl)trichlorosilane

A

75-77-4

chloro-trimethyl-silane

B

75-79-6

Methyltrichlorosilane

Conditions
ConditionsYield
at 500℃; for 0.00833333h;A 86.8%
B 91.2%
at 500℃; for 0.00833333h;A 91.2%
B 86.8%
13852-29-4

β-chlorovinyl(methyl)dichlorosilane

A

75-79-6

Methyltrichlorosilane

B

75-34-3

1,1-dichloroethane

C

75-01-4

chloroethylene

D

dichloro-(2,2-dichloro-ethyl)-methyl-silane

Conditions
ConditionsYield
With hydrogenchloride; iron(III) chloride at 25 - 31℃; for 4h; Product distribution; Further Variations:; Temperatures; reaction time, reagent concentration; Addition; elimination;A n/a
B n/a
C n/a
D 89%
7440-21-3

silicon

A

75-79-6

Methyltrichlorosilane

B

10026-04-7, 53609-55-5

tetrachlorosilane

C

10025-78-2

trichlorosilane

D

75-78-5

dimethylsilicon dichloride

Conditions
ConditionsYield
With methylene chloride; copper In neat (no solvent) mixt. of CH3Cl/N2 (2:5) and Si-Cu (9:1) at 300°C;;A 4%
B n/a
C n/a
D 86.5%
With methylene chloride; copper In neat (no solvent) mixt. of CH3Cl/N2 (2:5) and Si-Cu (9:1) at 300°C;;A 4%
B n/a
C n/a
D 86.5%
With methylene chloride; copper In neat (no solvent) CH3Cl and Si-Cu mixt. (8:2) at 350°C;;
1066-35-9

dimethylmonochlorosilane

1558-25-4

(chloromethyl)trichlorosilane

A

75-79-6

Methyltrichlorosilane

B

75-78-5

dimethylsilicon dichloride

Conditions
ConditionsYield
at 500℃; for 0.00833333h;A 79.1%
B 85.6%
74-87-3

methylene chloride

7440-21-3

silicon

A

75-54-7

Dichloromethylsilane

B

75-79-6

Methyltrichlorosilane

C

75-78-5

dimethylsilicon dichloride

Conditions
ConditionsYield
tin; aluminum silicide; zinc(II) oxide; copper dichloride at 280 - 300℃; for 6h; Rochow reaction;A 1.7%
B n/a
C 83.8%
zinc(II) oxide; copper dichloride at 280 - 300℃; for 6h; Rochow reaction;A 4.5%
B n/a
C 83.7%
zinc(II) oxide; aluminium; copper dichloride at 280 - 300℃; for 6h; Rochow reaction;A 2.8%
B n/a
C 82.1%
With PdSi at 400℃; for 6h;
74-87-3

methylene chloride

75-79-6

Methyltrichlorosilane

Conditions
ConditionsYield
With palladium silicide at 400 - 500℃; for 7.5h; Product distribution / selectivity; Inert atmosphere;82.8%
With aluminum oxide; trichlorosilane at 300℃; anschliessend Lieten ueber einen Kupfer-Silicium-Katalysator;
With Pd2Si at 400 - 500℃; for 7.5h; Inert atmosphere;
With amorphous silicon at 600 - 700℃; Inert atmosphere; Schlenk technique;
With hexachlorodisilane; tetrabutyl-ammonium chloride at -78 - 20℃; Inert atmosphere; Sealed tube;
1558-25-4

(chloromethyl)trichlorosilane

75-79-6

Methyltrichlorosilane

Conditions
ConditionsYield
With trichlorosilane at 500℃; for 0.00833333h;75.3%
74-87-3

methylene chloride

A

75-79-6

Methyltrichlorosilane

B

75-78-5

dimethylsilicon dichloride

Conditions
ConditionsYield
With tetrachlorosilane; palladium silicide; hydrogen at 400 - 850℃; for 5h; Product distribution / selectivity;A 74%
B 24%
With copper; silicon at 300 - 390℃;
With nitrogen; copper; silicon at 300 - 390℃;
7440-21-3

silicon

A

75-79-6

Methyltrichlorosilane

B

10026-04-7, 53609-55-5

tetrachlorosilane

Conditions
ConditionsYield
With methylene chloride In neat (no solvent) Si and a mixt. of CH3Cl and HCl (3:1) at 350°C;;A 72%
B n/a
7440-21-3

silicon

75-79-6

Methyltrichlorosilane

Conditions
ConditionsYield
With methylene chloride; copper In neat (no solvent) Si-Cu and a mixt. of CH3Cl, H2 and Cl2 at 350°C;;70.1%
With methylene chloride; iron(III) chloride In neat (no solvent)
With methylene chloride; copper In neat (no solvent) CH3Cl and unpurified Si;;
With methylene chloride; aluminium trichloride In neat (no solvent)
With methylene chloride; tin(IV) chloride In neat (no solvent)
75-76-3

tetramethylsilane

10038-98-9

germaniumtetrachloride

A

75-79-6

Methyltrichlorosilane

B

993-10-2

methyltrichlorogermane

C

75-78-5

dimethylsilicon dichloride

D

1529-48-2

dichlorodimethylgermanium

Conditions
ConditionsYield
aluminium bromide In neat (no solvent) molar ratio Me4Si/GeCl4 = 0.3/1, at 200°C for 65 h, cooled; NMR, mass spectra, chromy.;A 30%
B 68%
C 70%
D 32%
1185-55-3

Methyltrimethoxysilan

75-79-6

Methyltrichlorosilane

Conditions
ConditionsYield
With thionyl chloride; N,N-dimethyl-formamide at 55℃; under 760.051 Torr; for 2h;60%
With thionyl chloride; N,N-dimethyl-formamide at 55℃; for 2h; Reflux;60 %Spectr.
2031-67-6

Methyltriethoxysilan

75-79-6

Methyltrichlorosilane

Conditions
ConditionsYield
With thionyl chloride; N,N-dimethyl-formamide at 55℃; under 760.051 Torr; for 7h;60%
With thionyl chloride; N,N-dimethyl-formamide at 55℃; for 7h; Reflux;60 %Spectr.
1066-35-9

dimethylmonochlorosilane

75-78-5

dimethylsilicon dichloride

A

75-54-7

Dichloromethylsilane

B

75-77-4

chloro-trimethyl-silane

C

75-79-6

Methyltrichlorosilane

D

993-00-0

chloro-methyl-silane

Conditions
ConditionsYield
With aluminium trichloride at 140℃; for 15h;A 0.092 mol
B 59%
C 0.01 mol
D 0.055 mol
2372-31-8

triethenylsilane

1558-25-4

(chloromethyl)trichlorosilane

A

75-79-6

Methyltrichlorosilane

B

1871-21-2

chlorotrivinylsilane

Conditions
ConditionsYield
at 500℃; for 0.00833333h;A 41.5%
B n/a
74-87-3

methylene chloride

A

75-54-7

Dichloromethylsilane

B

75-79-6

Methyltrichlorosilane

C

75-78-5

dimethylsilicon dichloride

Conditions
ConditionsYield
With silicon; zinc at 325℃; for 24h; Reagent/catalyst; Inert atmosphere;A n/a
B n/a
C 41.1%
With copper(II) oxide; silicon; zinc at 325℃; for 24h; Reagent/catalyst; Inert atmosphere;A n/a
B n/a
C 17.5%
With silicon; bronze; cesium chloride; copper(l) chloride at 200 - 360℃; for 8h; Product distribution / selectivity;
67-66-3

chloroform

4518-98-3

1,1,2,2-tetrachloro-1,2-dimethyldisilane

A

75-79-6

Methyltrichlorosilane

B

1558-31-2

(dichloromethyl)methyldichlorosilane

Conditions
ConditionsYield
triphenylphosphineA n/a
B 35%
With triphenylphosphine at 140℃; for 4h;A 98 % Chromat.
B 29%
75-54-7

Dichloromethylsilane

A

75-79-6

Methyltrichlorosilane

B

1066-35-9

dimethylmonochlorosilane

C

993-00-0

chloro-methyl-silane

Conditions
ConditionsYield
dihydrogen hexachloroplatinate at 150℃; for 4h;A 25.1%
B 3.5%
C 2.9%
dihydrogen hexachloroplatinate at 150℃; for 4h;A 25.1%
B 3.5%
C 2.9%
18407-40-4

chloromethyl-methyl-diphenyl-silane

A

75-79-6

Methyltrichlorosilane

B

92-52-4

biphenyl

C

144-79-6

chloromethyldiphenylsilane

D

98-13-5

Phenyltrichlorosilane

E

107-06-2

1,2-dichloro-ethane

Conditions
ConditionsYield
iron(III) chloride at 70℃; for 0.5h; Product distribution; other conditions: other catalyst, other temperature;A 8%
B 10%
C 17%
D 14%
E 22%
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

1560-28-7

pentamethylchlorodisilane

4342-61-4

1,2-dichlorotetramethylsilane

13528-88-6

1,1,2-trichloro-1,2,2-trimethyldisilane

4518-98-3

1,1,2,2-tetrachloro-1,2-dimethyldisilane

4518-99-4

1,1-dichlorotetramethyldisilane

A

75-54-7

Dichloromethylsilane

B

75-77-4

chloro-trimethyl-silane

C

75-79-6

Methyltrichlorosilane

D

1066-35-9

dimethylmonochlorosilane

E

75-78-5

dimethylsilicon dichloride

Conditions
ConditionsYield
With hydrogenchloride at 430 - 750℃; for 72h; Conversion of starting material;A 4 %Chromat.
B 12 %Chromat.
C 7 %Chromat.
D 6 %Chromat.
E 21%
26980-40-5

methyl pentachlorodisilane

A

75-79-6

Methyltrichlorosilane

B

35483-48-8

1,1-Dichloro-1-methyl-disilane

C

1066-45-1

trimethyltin(IV)chloride

Conditions
ConditionsYield
With trimethylstannane; triphenylphosphine Ambient temperature;A 20%
B n/a
C n/a
75-79-6

Methyltrichlorosilane

102-53-4

bis-(diethylamino)methane

A

52853-18-6

N,N-diethyl(methylene)ammonium chloride

B

73221-33-7

(diethylamino)dichloromethylsilane

Conditions
ConditionsYield
In hexane for 5h; Ambient temperature;A 100%
B 59%
122-20-3

triisopropanolamine

75-79-6

Methyltrichlorosilane

1,3,7,10-Tetramethyl-2,8,9-trioxa-5-aza-1-sila-bicyclo[3.3.3]undecane; hydrochloride

Conditions
ConditionsYield
In dichloromethane100%
75-79-6

Methyltrichlorosilane

3789-85-3

2-[(trimethylsilyl)oxy]benzoic acid trimethylsilyl ester

A

75-77-4

chloro-trimethyl-silane

B

2-chloro-2-methyl-4H-benzo[d][1,3,2]dioxasilin-4-one

Conditions
ConditionsYield
at 20℃; for 24h;A 100%
B 95%
75-79-6

Methyltrichlorosilane

polymethylsilsesquioxane

polymethylsilsesquioxane

Conditions
ConditionsYield
With water In toluene at 50 - 60℃; Polymerization; hydrolytic polycondensation;99.6%
75-79-6

Methyltrichlorosilane

1185-55-3

Methyltrimethoxysilan

108-90-7

chlorobenzene

3027-21-2

dimethoxy(methyl)phenylsilane

Conditions
ConditionsYield
Stage #1: Methyltrimethoxysilan; chlorobenzene With magnesium In tetrahydrofuran for 1h; Reflux;
Stage #2: Methyltrichlorosilane; Methyltrimethoxysilan; chlorobenzene In tetrahydrofuran for 6.5h; Concentration; Reflux;
99.6%
75-79-6

Methyltrichlorosilane

103349-41-3

sodium tri-tert-butylsilanide

Dichlormethylsupersilylsilan

Conditions
ConditionsYield
In tetrahydrofuran at -78℃; Substitution; supersilanidation;99%
75-79-6

Methyltrichlorosilane

346713-20-0

allylsamarium bromide

1873-92-3

allyldichloromethylsilane

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 1.5h;99%
75-79-6

Methyltrichlorosilane

141-52-6

sodium ethanolate

2031-67-6

Methyltriethoxysilan

Conditions
ConditionsYield
In ethanol for 3h;99%
75-79-6

Methyltrichlorosilane

64-17-5

ethanol

2031-67-6

Methyltriethoxysilan

Conditions
ConditionsYield
With polyaniline at 50 - 55℃; for 5h;98.3%
75-79-6

Methyltrichlorosilane

1558-25-4

(chloromethyl)trichlorosilane

Conditions
ConditionsYield
With chlorine Irradiation;98%
With chlorine at 65℃; for 6.5h; Irradiation; visible light;68%
With chlorine im UV-Licht;
75-79-6

Methyltrichlorosilane

54220-62-1

N-2,6-triethylphenylsalicylaldimine

C52H57N3O3Si

Conditions
ConditionsYield
With triethylamine In benzene for 2h; Heating;98%
75-79-6

Methyltrichlorosilane

3-tert-butylperoxy-1,2-epoxypropane

methyl-tris(3-tert-butylperoxy-1-chloro-2-propyloxy)silane

Conditions
ConditionsYield
at 30 - 35℃; for 4.5h;98%
75-79-6

Methyltrichlorosilane

533-58-4

2-Iodophenol

17881-58-2

2-iodo(trimethylsilyloxy)benzene

Conditions
ConditionsYield
With pyridine In benzene heating of (CH3)3SiCl and HOC6H4I in benzene in presence of pyridine;;98%
With pyridine In benzene heating of (CH3)3SiCl and HOC6H4I in benzene in presence of pyridine;;98%
2637-34-5

2-Mercaptopyridine

75-79-6

Methyltrichlorosilane

chloromethylbis[N,S-pyridine-2-thiolato]silicon(IV)

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran at 20℃; for 24h; Inert atmosphere; Schlenk technique;98%
75-79-6

Methyltrichlorosilane

N,N-bis(2-trimethylsiloxyethyl)glycine methyl(trimethylsilyl)amide

1,2-dimethyl-2-azasilatran-3-one

Conditions
ConditionsYield
With quinoline In benzene at 80℃; for 5h; Reagent/catalyst; Solvent; Temperature; Time; Inert atmosphere;98%
75-79-6

Methyltrichlorosilane

2031-67-6

Methyltriethoxysilan

1825-75-8

ethoxy(methyl)dichlorosilane

Conditions
ConditionsYield
at 200℃; for 6h; Temperature; Molecular sieve; Large scale;98%
With bismuth(III) chloride at 25℃; for 24h; Inert atmosphere;85%
With bismuth(III) chloride at 20℃; for 24h; Schlenk technique; Inert atmosphere;50 mol
75-79-6

Methyltrichlorosilane

17760-13-3

trichloromethyltrichlorosilane

Conditions
ConditionsYield
With chlorine In tetrachloromethane Irradiation;97%
With Cl2 In chloroform CH3SiCl3 and Cl2 in CHCl3 below 25°C;; sublimation under reduced pressure;;95%
With chlorine In chloroform CH3SiCl3 and Cl2 in CHCl3 above 70°C;;55%
75-79-6

Methyltrichlorosilane

2078-54-8

2,6-diisopropylphenol

C37H54O3Si

Conditions
ConditionsYield
With pyridine In benzene 1.) RT, 12 h, 2.) reflux, 1 h;97%
103-83-3

N,N'-dimethylbenzylamine

75-79-6

Methyltrichlorosilane

131120-56-4

[2-(dimethylaminomethyl)phenyl]methyldichlorosilane

Conditions
ConditionsYield
With n-butyllithium; tetrachlorosilane In diethyl ether; hexane at 25℃;97%
89-72-5

2-sec-butylphenol

75-79-6

Methyltrichlorosilane

C31H42O3Si

Conditions
ConditionsYield
With triethylamine In benzene97%
75-79-6

Methyltrichlorosilane

499-75-2

carvacrol

66760-15-4

C31H42O3Si

Conditions
ConditionsYield
With triethylamine In benzene97%
75-79-6

Methyltrichlorosilane

787-94-0

N-2,4,6-trimethylphenylsalicylaldimine

[1-[2-(Dichloro-methyl-silanyloxy)-phenyl]-meth-(E)-ylidene]-(2,4,6-trimethyl-phenyl)-amine

Conditions
ConditionsYield
With triethylamine In benzene for 2h; Heating;97%
75-79-6

Methyltrichlorosilane

54220-52-9

2-(((2,6-dimethylphenyl)imino)methyl)phenol

C31H31ClN2O2Si

Conditions
ConditionsYield
With triethylamine In benzene for 2h; Heating;97%
75-79-6

Methyltrichlorosilane

848475-32-1

6-Dimethylsilanyl-hexan-2-ol

848475-37-6

CH3Si(OCHCH3(CH2)4Si(CH3)2H)3

Conditions
ConditionsYield
With triethylamine In diethyl ether at 25℃;97%
75-79-6

Methyltrichlorosilane

346713-20-0

allylsamarium bromide

1112-91-0

methyltriallylsilane

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 1.5h;97%
75-79-6

Methyltrichlorosilane

1262286-31-6

N,N-dimethylamide O-SiMe3-(S)-lactic acid

bis[1-(dimethylcarbamoyl)ethoxy]methylsilylium chloride

Conditions
ConditionsYield
In hexane97%
75-79-6

Methyltrichlorosilane

N'-(trimethylsilyl)-N,N-bis{2-[(trimethylsilyl)oxy]ethyl}glycinamide

1-methyl-2-azasilatran-3-one

Conditions
ConditionsYield
With quinoline In benzene at 80℃; for 5h; Reagent/catalyst; Solvent; Temperature; Time; Inert atmosphere;97%
75-79-6

Methyltrichlorosilane

6280-87-1

δ-chlorovaleronitrile

18135-77-8

5-(dichloro-methyl-silanyl)-valeronitrile

Conditions
ConditionsYield
With magnesium; ethylene dibromide; manganese(ll) chloride In toluene at 70℃; for 4h; Solvent; Temperature; Inert atmosphere;96.7%
542-76-7

3-Chloropropionitrile

75-79-6

Methyltrichlorosilane

1071-21-2

dichloro(2-cyanoethyl)methylsilane

Conditions
ConditionsYield
With magnesium; ethylene dibromide; manganese(ll) chloride In tetrahydrofuran at 50℃; for 2h; Inert atmosphere;96.6%
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    Address:9/F, Unit 2 Changdi Torch Building, 259# WenSan Road, Xihu District, Hangzhou City 310012, P.R.China

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    Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

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    Business Type:Lab/Research institutions

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    Address:Zhengzhou International Trade New Territory,Jinshui District,Zhengzhou ,China

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    Business Type:Trading Company

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    Business Type:Trading Company

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    Business Type:Lab/Research institutions

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    Address:Weiyang District

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    Business Type:Trading Company

    Tel:+8613397160123

    Address:13th Floor, Tower B, Century Plaza, Zhongnan Road, Wuchang District, Wuhan, China.

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    Methyltrichlorosilane Englishname:Methyltrichlorosilane EnglishSynonyms:Trichloromethylsilane CASNo.:75-79-6[1]EINECSNo.:200-902-…

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     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:86-543-8178171

    Address:428 Daixi Third Road Zouping County Shandong Province China

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    Business Type:Trading Company

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    75-79-6

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    Business Type:Lab/Research institutions

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    Address:Building 3 of Innovation Park, East District of the National University Science Park

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    Why Choose Us: 1.Own chemical factory 2.Abundant professional production experience 3.Sample is free of charge and in stock with fast delivery 4.Price,quality&service,we care that all your cares 5.Prompt reply keep in touch to sa

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     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:0086-15530135359

    Address:QiaoXiQu

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    1. Subsidiary of Institute of Chemistry, Henan Academy of Sciences, national research platform;2. About 30 years’ experience in this field since 1983;3. An experienced R&D team consisting of Doctors and Masters;4. Various types of analytical instrume

    Zhengzhou Kingorgchem Chemical Technology Co., Ltd. was founded on the basis of Organophosphorus Chemistry Lab of Institute of Chemistry Henan Academy of Sciences in 2015. The

  •  Zhengzhou Kingorgchem Chemical Technology Co., Ltd.

     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-371-65511936

    Address:NO.56,Hongzhuan Road

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    75-79-6

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    Appearance:white or yellowish white flaky crystal Storage:Keep the sun from direct sunlight ;prevention against high temperature Package:As customer request Application:Used for research and industrial manufacture. Transportatio

    Triumph International Development Limilted is engaged in the API, pharmaceutical intermediates research and developmen.Adhering to the "customer first" business philosophy,we suppl

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    China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-536-7971999

    Address:Yinhai Road,Shouguang

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    Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

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     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:18369939125

    Address:95A, Xingyuan East Road, Zhangdian District

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    Business Type:Lab/Research institutions

    Tel:+86-571-87396432

    Address:No.200 Zhenhua Rd.Xihu Industrial Park, Hangzhou 310030, China

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    Business Type:Trading Company

    Tel:0532-80916960

    Address:shandong qingdao

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    HangYu Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. HangYu Chemical consis

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  •  Zibo Hangyu Import&Export Co., Ltd

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    Business Type:Lab/Research institutions

    Tel:86-15988566987

    Address:Room1701, Tianxing Building,Licheng district, jinan, Shandong, China

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    Business Type:Other

    Tel:+86 592 605 6448

    Address:No.31 Pingshan South Road, HaiCang District, Xiamen, China

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    Business Type:Lab/Research institutions

    Tel:86-15821988213

    Address:Dalian Rd 950th

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    Business Type:Other

    Tel:86-27-85736489

    Address:Rm. 1503, No. 164, Jianghan North Rd., Wuhan, 430022 China

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    Changsha EASCHEM is a leading company in marketing ang distributing chemicals and new materials with establishment in 2013 by reregistering from Easchem International from China. We, EASCHEM, are the brand with the aim for erecting up Big Chemica

    Changsha EASCHEM is a leading company in marketing ang distributing chemicals and new materials with establishment in 2013 by reregistering from Easchem International from China.

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    Business Type:Lab/Research institutions

    Tel:+86-731-89722861 89722891

    Address:2/F-4/Bld Colorful Palace, No.605 Changsha Ave, Yuhua Area Changsha Hunan China.

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    Business Type:Lab/Research institutions

    Tel:+86-533-2362027

    Address:No. 416, 4th floor, zhongguancun science and technology city, no. 1, west 6th road, zhangdian district

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    Business Type:Trading Company

    Tel:86-571-56972507

    Address:Room 4198,Floor 4,No.4,ShanXian Road XiaCheng District,HangZhou city,ZheJiang province,China

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    Kono Chem Co.,Ltd is a leading producer of standardized herbal extracts, natural active ingredients and APIs for pharmaceutical, health food and cosmetic industries. Annually, mo

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    Business Type:Other

    Tel:86-29-86107037-8015

    Address:No.11 Daqing Road,Lianhu District,Xi’an 710082,China

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    GIHI CHEMICALS CO.,LIMITED, its former company is a small manufacturer who is specialized in the production of ester products which are used in the daily chemicals ,cosmetic produc

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     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:571-86217390

    Address:Huacai International Building,Sandun,Westlake District,Hangzhou 310030,Zhejiang,China

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    75-79-6

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    Business Type:Lab/Research institutions

    Tel:86-579-82660891

    Address:47-204 No.288, Shida St., Wuchem Dist., Jinhua,Zhejiang, 321004 China

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    Hangzhou Dingyan Chem Co., LTD. is located in the beautiful tourist city of hangzhou, is a comprehensive chemical enterprice which doing import and export business by its own comp

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    Business Type:Manufacturers

    Tel:86-571-86465881,86-571-87157530,86-571-88025800

    Address:RM.1118,NO.1 Building, Baiyun Tower,Jianggan Area, Hangzhou city, China,310004

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    75-79-6

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    Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

    Xiamen Aeco Chemical Industrial Co., Ltd(same as Aecochem Corp.) An ISO 9001:2015 Certified Company Your Partner in China, a Professional chemical raw material supplier, our

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    Business Type:Manufacturers

    Tel:+86-592 599 8717

    Address:No 611 Sishui Road,Huli

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    75-79-6

    Trichloro(Methyl)silane

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  • Methyltrichlorosilane

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    Methyltrichlorosilane

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  • Methyltrichlorosilane

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    Methyltrichlorosilane

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Chemistry

The Molecular Structure of Methyltrichlorosilane (CAS NO.75-79-6):

Empirical Formula: CH3Cl3Si
Molecular Weight: 149.479 
IUPAC Name: trichloro(methyl)silane 
Appearance: Colorless clear liquid
Nominal Mass: 148 Da
Average Mass: 149.479 Da
Monoisotopic Mass: 147.906959 Da 
Index of Refraction: 1.434
Molar Refractivity: 29.94 cm3
Molar Volume: 114.9 cm3
Surface Tension: 21.1 dyne/cm
Density: 1.3 g/cm3
Enthalpy of Vaporization: 30.17 kJ/mol
Boiling Point: 73.5 °C at 760 mmHg
Vapour Pressure: 124 mmHg at 25°C 
Storage temp: Flammables area
Water Solubility: REACTS
FreezingPoint:  -77.8°C 
Melting Point: -77°C 
Flash Point: -13°C 
Sensitive: Moisture Sensitive
Stability: Stable, but reacts violently with water. Highly flammable. Incompatible with moisture, water, strong bases, strong acids, strong oxidizing agents
InChI
InChI=1/CH3Cl3Si/c1-5(2,3)4/h1H3
Smiles
[Si](C)(Cl)(Cl)Cl 
Synonyms: Methyl silicochloroform ; Methylsilicon trichloride ; Methylsilichloroform ; Methylsilyltrichloride  
Product Categories: Chloro;Organics;Biochemistry;Functional Materials;Reagents for Oligosaccharide Synthesis;Si (Classes of Silicon Compounds);Si-Cl Compounds;Silane Coupling Agents;Silane Coupling Agents (Intermediates);Silicon Compounds (for Synthesis);Synthetic Organic Chemistry;Trichlorosilanes;Chloro Silanes

Uses

 Methyltrichlorosilane (CAS NO.75-79-6) is mainly used a precursor for forming various cross-linked siloxane polymers. Methyltrichlorosilane (CAS NO.75-79-6) is mainly used to form polymers such as poly(methylsilyne). Esters and lactones can also be cleaved with methyltrichlorosilane and sodium iodide to give the corresponding carboxylic acids . Acetals convert to carbonyl compounds.Thus, Methyltrichlorosilane (CAS NO.75-79-6)can be used to remove acetal protecting groups from carbonyl compounds under mild conditions. Finally, Methyltrichlorosilane (CAS NO.75-79-6) and sodium iodide can be used as a means of converting alcohols to their corresponding iodides.

Production

 Methyltrichlorosilane (CAS NO.75-79-6) results from the "direct reaction" of chloromethane with elemental silicon in the presence of a copper catalyst, usually at a temperature of at least 250 °C.
3 CH3Cl + Si → CH3SiCl3 + C2H4 + H2 
While this reaction is currently the standard in industrial silicone production and is nearly identical to the first direct synthesis of methyltrichlorosilane, the overall process is inefficient with respect to methyltrichlorosilane.

Toxicity Data With Reference

1.    

skn-rbt 500 µL SEV

    JACTDZ    Journal of the American College of Toxicology. 12 (1993),571.
2.    

eye-rbt 5 mg/24H SEV

    85JCAE    Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,1219.
3.    

orl-rat LD50:1620 µL/kg

    JACTDZ    Journal of the American College of Toxicology. 12 (1993),571.
4.    

ihl-rat LC50:450 ppm/4H

    85JCAE    Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,1219.
5.    

ipr-rat LDLo:30 mg/kg

    JIDHAN    Journal of Industrial Hygiene. 30 (1948),332.
6.    

ihl-mus LC50:180 mg/m3/2H

    TPKVAL    Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Sciences. 3 (1961),23.
7.    

skn-rbt LD50:840 µL/kg

    JACTDZ    Journal of the American College of Toxicology. 12 (1993),571.

Poison by inhalation and intraperitoneal routes. Moderately toxic by ingestion. A severe irritant to skin, eyes, and mucous membranes. Flammable when exposed to heat or flame; can react vigorously with oxidizing materials. When heated to decomposition it emits toxic fumes of Cl. See also CHLOROSILANES.