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7789-60-8

Basic Information
CAS No.: 7789-60-8
Name: Phosphorus tribromide
Molecular Structure:
Molecular Structure of 7789-60-8 (Phosphorus tribromide)
Formula: Br3P
Molecular Weight: 270.69
Synonyms: tribromophosphane;Phosphorous tribromide;Tribromophosphine;Phosphorus bromide (PBr3);Phosphorous bromide;Phosphorus tribromide [UN1808] [Corrosive];phosphorum tribromide;Phosphlrus tribromide;Phosphoric tribromide;Phosphorusbromide;
EINECS: 232-178-2
Density: 2.88 g/mL at 20 °C(lit.)
Melting Point: -40 °C
Boiling Point: 172.9 °C at 760 mmHg
Flash Point: 172.9°C
Solubility: reacts with water
Appearance: colorless fuming liquid with a pungent odor
Hazard Symbols: CorrosiveC
Risk Codes: 34-37-40-14
Safety: 26-45-36/37/39
Transport Information: UN 3264 8/PG 2
PSA: 13.59000
LogP: 3.39800
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Chemistry

Molecular Structure:

Molecular Formula: H8Br3P
Molecular Weight: 278.7493
IUPAC Name: Tribromophosphane
Synonyms of Phosphorus tribromide (CAS NO.7789-60-8): EINECS 232-178-2 ; HSDB 1217 ; Phosphorous bromide ; Phosphorus bromide (PBr3) ; Phosphorus tribromide ; Tribromophosphine ; Phosphorus tribromide [UN1808] [Corrosive] ; UN1808
CAS NO: 7789-60-8
Product Categories: Inorganics ; BrominationMicro/Nanoelectronics ; C-X Bond Formation (Halogen) ; Electronic Chemicals ; Others ; Synthetic Reagents
Melting point: -40 °C
SMILES: [PH6+3].[Br-].[Br-].[Br-] 
InChI: InChI=1/3BrH.P/h3*1H;/q;;;+3/p-3 
InChIKey: BEXNWOOMHDDWHU-DFZHHIFOAC
Std. InChI: InChI=1S/3BrH.P/h3*1H;/q;;;+3/p-3 
Std. InChIKey: BEXNWOOMHDDWHU-UHFFFAOYSA-K

Uses

 Phosphorus tribromide (CAS NO.7789-60-8) is used in organic synthesis, used as a brominating agent and reducing agent, etc.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rat LDLo oral 50mg/kg (50mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: MUSCLE WEAKNESS

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
National Technical Information Service. Vol. OTS0555394,

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Probably highly toxic. A corrosive irritant to the eyes, skin, and mucous membranes. Will react with water, steam, or acids to produce heat, toxic and corrosive fumes. Violent reaction or ignition with calcium hydroxide + sodium carbonate, phenylpropanol, sulfuric acid, oleum, fluorosulfuric acid, chlorosulfuric acid, 1,1,1-tris(hydroxymethyl)methane, water, potassium, sodium, RuO4. When heated to decomposition it emits very toxic fumes of Br and POx. See also PHOSPHIDES and BROMIDES.
Hazard Codes of Phosphorus tribromide (CAS NO.7789-60-8): CorrosiveC
Risk Statements: 34-37-40-14 
R34: Causes burns. 
R37: Irritating to respiratory system 
R40: Limited evidence of a carcinogenic effect. 
R14: Reacts violently with water.
Safety Statements: 26-45-36/37/39 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
RIDADR: UN 3264 8/PG 2
WGK Germany: 2
RTECS: TH4460000
F: 21
HazardClass: 8
PackingGroup: II

Standards and Recommendations

DOT Classification:  8; Label: Corrosive

Specification

Chemical Stability: Moisture sensitive. 
Conditions to Avoid: Incompatible materials, exposure to moist air or water. 
Incompatibilities with Other Materials Strong oxidizing agents. 
Hazardous Decomposition Products Carbon monoxide, oxides of phosphorus, carbon dioxide, hydrogen bromide. 
Hazardous Polymerization Has not been reported.