102-87-4 Usage
Chemical Properties
Clear slightly yellow liquid. Soluble in organic solvents; insoluble in water. Combustible.
Uses
Different sources of media describe the Uses of 102-87-4 differently. You can refer to the following data:
1. Chemical intermediate, metal complexes.
2. TRIDODECYLAMINE (cas# 102-87-4) is a tertiary fatty amine which has been used in the preparation of an embedded telemetry system for potentiometric sensors, and in the preparation of gemini cationic surfactant-based ionic liquids.
3. Tridodecylamine(TDA) can be used in the following applications:Extraction of picolinic acid, citric acid, silver, mercury, selenium, zinc, cobalt, iron and succinic acid from aqueous solutions by using various organic solvents as diluents.Recovery of Remazol Red 3BS (R3BS) dye from wastewater via emulsion liquid membrane (ELM) process by using TDA as the carrier agent.Synthesis of gemini surfactant-based ionic liquids by reacting with dibromo alkanes.
General Description
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Purification Methods
Distil tridodecylamine under high vacuum and N2, and store it in the absence of CO2. It can be crystallised from 95%EtOH/*C6H6 at low temperature under vacuum. The hydrochloride has m 78-79o. [Ra et al. J Org Chem 9 259 1944, Beilstein 4 III 413, 4 IV 801.]
Check Digit Verification of cas no
The CAS Registry Mumber 102-87-4 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 1,0 and 2 respectively; the second part has 2 digits, 8 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 102-87:
(5*1)+(4*0)+(3*2)+(2*8)+(1*7)=34
34 % 10 = 4
So 102-87-4 is a valid CAS Registry Number.
InChI:InChI=1/C36H75N/c1-4-7-10-13-16-19-22-25-28-31-34-37(35-32-29-26-23-20-17-14-11-8-5-2)36-33-30-27-24-21-18-15-12-9-6-3/h4-36H2,1-3H3
102-87-4Relevant articles and documents
Selectivity control in substituted fatty amines synthesis from esters or nitriles in the presence of bifunctional catalysts
Barrault,Brunet,Suppo-Essayem,Piccirilli,Guimon
, p. 1231 - 1238 (1994)
Copper chromite-type catalysts, supported by alumina or graphite and promoted with barium, were used for the one-step synthesis of tertiary fatty amines [R2NCH3 or RN(CH3)2] from ester, acid or nitrile and ammonia, methanol and hydrogen. The surface composition of the catalysts, studied by X-ray photoelectron spectroscopy and by adsorption experiments, showed that there was a correlation between selectivity and the presence of a well-dispersed CuCrO2 phase, stabilized with barium. Moreover, the elements influencing the stability of the copper catalysts were also studied, and the promoter or/and the support increased the copper surface area and the stability of the catalyst in the presence of water or ammonia.
Alkyl substituent effect on the polarity of phenols-tri-n-alkylamine complexes
Pawelka, Zbigniew,Zeegers-Huyskens, Therese
, p. 1012 - 1018 (2007/10/03)
The formation constants and the dipole moments of the H-bonded adducts of 1:1 and 2:1 stoichiometries formed between three different phenols (phenol, 2,4,6-trichlorophenol, and 2,4-dinitrophenol) and different tri-n-alkylamines are determined in solvents
Amine oxide process
-
, (2008/06/13)
A process for accelerating the oxidation of tert-amines by hydrogen peroxide by conducting the reaction in the presence of an ascorbic acid promoter.