13048-17-4

Basic information

• Product Name: 2-Cyclohexene-1-carbonitrile
• Synonyms: 2-Cyclohexene-1-carbonitrile;1-CYANO-2-CYCLOHEXENE
• CAS NO: 13048-17-4
• Molecular Formula: C₇H₉N
• Molecular Weight: 107.15
• Mol File: 13048-17-4.mol
• Article Data: 17

Chemical Properties

• Boiling Point: 200.9°Cat760mmHg
• Flash Point: 65.8°C
• Appearance: /
• Density: 0.94g/cm³
• Vapor Pressure: 0.317mmHg at 25°C
• Refractive Index: 1.481
• CAS DataBase Reference: 2-Cyclohexene-1-carbonitrile(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclohexene-1-carbonitrile(13048-17-4)
• EPA Substance Registry System: 2-Cyclohexene-1-carbonitrile(13048-17-4)

Safety Data

• Hazardous Substances Data: 13048-17-4(Hazardous Substances Data)

Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 58, p. 16, 1993 DOI: 10.1021/jo00053a007

InChI:InChI=1/C7H9N/c8-6-7-4-2-1-3-5-7/h2,4,7H,1,3,5H2

Upstream product

• 77786-76-6 2-Methyl-1-(tricyclo<4.1.0.0^2,7>hept-1-yl)aziridin 
• 77786-77-7 cis-2,3-Dimethyl-1-(tricyclo<4.1.0.0^2,7>hept-1-yl)aziridin 
• 151-50-8 potassium cyanide 
• 1521-51-3 rac-3-bromocyclohexene 
• 1165952-91-9 cyclohexa-1,3-diene 
• 55305-43-6 N-cyano-N-phenyl-p-toluenesulfonamide 
• 872-50-4 1-methyl-pyrrolidin-2-one 
• 773837-37-9 sodium cyanide 
• 10442-39-4 tetra-n-butylammonium cyanide 
• 143-33-9 sodium cyanide 
• 2408-36-8 lithium cyanide 
• 74-90-8 hydrogen cyanide 
• 70302-49-7 1-(Tricyclo<4.1.0.0^2,7>hept-1-yl)aziridin 
• 98098-44-3 1-Cyanocyclohex-2-enyl diethyl phosphate 

Downstream Products

• 108125-57-1 7-(3-carboxy-phenyl)-heptanoic acid 
• 1888-90-0 3-methylene-cyclohexene 
• 40391-15-9 methyl N-(2-cyclohexen-1-ylmethyl)carbamate 
• 40391-16-0 C₉H₁₄N₂O₃ 
• 1273587-36-2 (E)-3-(hex-1-en-1-yl)cyclohex-1-enecarbonitrile 
• 1273587-35-1 (Z)-3-(hex-1-en-1-yl)cyclohex-1-enecarbonitrile 
• 583-60-8 2-Methylcyclohexanone 
• 4065-80-9 2-methylenecyclohexanol 
• 4845-04-9 1-cyclohexene-1-methanol 
• 101099-29-0 7-(3-carboxy-cyclohexyl)-heptanoic acid 
• 29372-98-3 1-acetyl-2-cyclohexene 
• 103668-33-3 3-hydroxymethylcyclohexene 
• 66333-29-7 3-hydroxycyclohex-1-enecarbonitrile 
• 32917-21-8 Cyclohex-1-enylmethyl-[1-cyclohex-1-enyl-meth-(E)-ylidene]-amine 

Relevant articles and documents

NON-AQUEOUS CYANATION OF HALIDES USING LITHIUM CYANIDE

Efficient conversion of various halides into the corresponding nitriles with lithium cyanide in tetrahydrofuran is described.

Michael addition of cyanide to cyclohex-1-enyliodonium salts

Reaction of 4-substituted cyclohex-1-enyliodonium salt with cyanide in chloroform produces three isomeric cyanocyclohexenes, ipso and two cine products. Deuterium labeling experiments showed that the allylic cine product is formed via the Michael addition of cyanide, followed by elimination of the iodonio group and a 1,2-H shift.

Electrophilic cyanation of allylic boranes: Synthesis of β,γ-unsaturated nitriles containing allylic quaternary carbon centers

The electrophilic cyanation of allylic boranes, a process that is applicable to the construction of allylic quaternary carbon centers, is reported. The reaction has a broad substrate scope with a high functional group tolerance. The results represent an u

Nickel(0)-catalyzed asymmetric hydrocyanation of 1,3-dienes

1,2-Bis-diarylphosphinites are excellent ligands for the Ni(0)-catalyzed hydrocyanation of certain types of 1,3-dienes. 1-Phenyl-1,3-butadiene, 1-vinyl-3,4-dihydronaphthalene, and 1-vinylindene undergo highly regioselective hydrocyanation under ambient co