15690-24-1

Basic information

• Product Name: (E)-3-(furan-2-yl)acrylic acid
• Synonyms: (E)-3-FURAN-2-YL-ACRYLIC ACID;-3-(Furan-2-yl)
• CAS NO: 15690-24-1
• Molecular Formula: C7H6O3
• Molecular Weight: 138.12
• Mol File: 15690-24-1.mol
• Article Data: 81

Chemical Properties

• Boiling Point: 286 °C at 760 mmHg
• Flash Point: 106.8 °C
• Appearance: /
• Density: 1.28 g/cm³
• Storage Temp.: Sealed in dry,Room Temperature
• CAS DataBase Reference: (E)-3-(furan-2-yl)acrylic acid(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-3-(furan-2-yl)acrylic acid(15690-24-1)
• EPA Substance Registry System: (E)-3-(furan-2-yl)acrylic acid(15690-24-1)

Safety Data

• Hazardous Substances Data: 15690-24-1(Hazardous Substances Data)

Usage

General Description

(E)-3-(furan-2-yl)acrylic acid, also known as furan-2-carboxylic acid, is a chemical compound with the molecular formula C6H4O3. It is a carboxylic acid that contains a furan ring, which is a heterocyclic organic compound. (E)-3-(furan-2-yl)acrylic acid has a molecular structure consisting of a furan ring attached to an acrylate group, which gives it its unique properties. It is commonly used in organic synthesis, pharmaceuticals, and as a building block in the production of various chemical compounds. Its unique structure and properties make it a valuable compound for research and industrial applications.

Upstream product

• 98-01-1 furfural 
• 127-08-2 potassium acetate 
• 127-09-3 sodium acetate 
• 108-24-7 acetic anhydride 
• 539-66-2 sodium isovalerate 
• 141-82-2 malonic acid 
• 56-40-6 glycine 
• 302-72-7 rac-Ala-OH 
• 623-15-4 4-(furan-2-yl)but-3-en-2-one 
• 623-15-4 (E)-4-(furan-2-yl)but-3-en-2-one 
• 53282-12-5 ethyl (E)-3-(2-furyl)prop-2-enoate 
• 105-53-3 diethyl malonate 
• 4440-16-8 2-(2-furanylmethylene)-propanedioic acid 
• 110-89-4 piperidine 

Downstream Products

• 104431-32-5 2-(4-Nitrophenyl)-1-(5-(4-nitrophenyl)-2-furyl)ethylene 
• 129626-56-8 2-(4-chloro-phenyl)-5-(4-chloro-styryl)-furan 
• 58293-85-9 methyl 3-(2-furyl)acrylate 
• 100725-90-4 N-benzoyl-O-(3t-[2]furyl-acryloyl)-hydroxylamine 
• 175165-68-1 C₁₄H₉NO₂ 
• 73353-76-1 Furanacryloylglycine methyl ester 
• 67229-90-7 (E)-1-(furan-2-yl)-2-phenylsulfonylethene 
• 39511-12-1 (E)-3-(furan-2-yl)-1-phenyl-2-propen-1-one 

Relevant articles and documents

Biomass-derived rctt-3,4-di-2-furanyl-1,2-cyclobutanedicarboxylic acid: a polytopic ligand for synthesizing green metal-organic materials

Biomass is an abundant and environmentally friendly source for materials that can be used in a multitude of applications in the effort to replace petrochemicals. Furfural and malonic acid are biomass-sourced platforms that can be utilized in the synthesis of biobased compounds; rctt-3,4-di-2-furanyl-1,2-cyclobutanedicarboxylic acid (CBDA-2) is one such compound. In this study, CBDA-2 has been introduced into metal-organic materials chemistry as a semi-rigid polytopic ligand. This compound has been utilized as a polytopic ligand in the formation of two different 2D coordination polymers with Cu2+ and Co2+ as the metal centers via a conventional solution method. Both complexes have been characterized by X-ray crystal structure determination and showed visual thermochromic behaviors. This study demonstrates that CBDA-2 is a promising green building block in coordination chemistry.

Sulfuric acid and Amberlyst-H+ catalyzed condensation reactions of renewable keto acids with paraformaldehyde: Synthesis of a new dispiro bis-lactone ring system 2,9,13-trioxadispiro[4.1.4.3]tetradecane-3,6,10-trione

The sulfuric acid and Amberlyst-H+ catalyzed condensation reactions of renewable feedstock levulinic acid with paraformaldehyde under neat conditions at 80 °C gives 2,9,11,14-tetraoxadispiro[4.1.5.3]pentadecane-3,6-dione in 91-93% yield, in which the structure was confirmed by single crystal X-ray crystallography. A similar condensation reaction between 4-ketopimelic acid and paraformaldehyde at 80 °C gives 2,9,13-trioxadispiro[4.1.4.3]tetradecane-3,6,10-trione. This new dispiro bis-lactone was found to composed of a 1.6 : 1 mixture of isomers with planes of symmetry bisecting the tetrahydro-2H-pyran-4-one rings through the carbonyl groups.

Chlorination Reaction of Aromatic Compounds and Unsaturated Carbon-Carbon Bonds with Chlorine on Demand

Chlorination with chlorine is straightforward, highly reactive, and versatile, but it has significant limitations. In this Letter, we introduce a protocol that could combine the efficiency of electrochemical transformation and the high reactivity of chlorine. By utilizing Cl3CCN as the chloride source, donating up to all three chloride atom, the reaction could generate and consume the chlorine in situ on demand to achieve the chlorination of aromatic compounds and electrodeficient alkenes.

Iron-catalyzed domino decarboxylation-oxidation of α,β-unsaturated carboxylic acids enabled aldehyde C-H methylation

A practical and general iron-catalyzed domino decarboxylation-oxidation of α,β-unsaturated carboxylic acids enabling aldehyde C-H methylation for the synthesis of methyl ketones has been developed. This mild, operationally simple method uses ambient air as the sole oxidant and tolerates sensitive functional groups for the late-stage functionalization of complex natural-product-derived and polyfunctionalized molecules.