59101-32-5

Basic information

• Product Name: Benzamide, N-(benzoyloxy)-4-methoxy-
• Synonyms: Anishydroxamsaeure-benzoat;O-benzoyl-N-(4-methoxy-benzoyl)-hydroxylamine;4-Methoxy-N-benzoyloxy-benzamid;O-Benzoyl-N-anisoyl-hydroxylamin;Anisbenzhydroxamsaeure;Benzamide,N-(benzoyloxy)-4-methoxy;4-Methoxy-O-benzoyl-benzohydroxamsaeure
• CAS NO: 59101-32-5
• Molecular Formula: C15H13NO4
• Molecular Weight: 271.273
• Mol File: 59101-32-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzamide, N-(benzoyloxy)-4-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzamide, N-(benzoyloxy)-4-methoxy-(59101-32-5)
• EPA Substance Registry System: Benzamide, N-(benzoyloxy)-4-methoxy-(59101-32-5)

Safety Data

• Hazardous Substances Data: 59101-32-5(Hazardous Substances Data)

Upstream product

• 10507-69-4 4-methoxybenzohydroxamic acid 
• 98-88-4 benzoyl chloride 
• 60-29-7 diethyl ether 
• 532-31-0 silver benzoate 
• 38435-51-7 N-hydroxy-4-methoxy-benzenecarboximidoyl chloride 
• 94-36-0 dibenzoyl peroxide 
• 860584-94-7 (+/-)-4-(chloro-nitroso-methyl)-anisole 
• 3717-21-3 (E)-4-methoxybenzaldoxime 
• 3717-22-4 (Z)-para-methoxybenzaldehyde oxime 
• 100-09-4 4-methoxybenzoic acid 
• 100-07-2 4-methoxy-benzoyl chloride 
• 7647-01-0 hydrogenchloride 
• 108-90-7 chlorobenzene 
• 57139-22-7 potassium p-methoxylbenzohydroxamate 

Downstream Products

• 7472-54-0 N-(p-methoxyphenyl)benzamide 
• 104-94-9 4-methoxy-aniline 
• 10507-69-4 4-methoxybenzohydroxamic acid 
• 65-85-0 benzoic acid 
• 1227-44-7 N,N'-bis(4-methoxyphenyl)urea 
• 5416-93-3 4-Methoxyphenyl isocyanate 
• 124-38-9 carbon dioxide 

Relevant articles and documents

A very mild and selective method for O-benzoylation of hydroxamic acids

Selective O-benzoylation of hydroxamic acids is achieved by the treatment of BPO and DABCO. Aliphatic alcohols are not reactive under these conditions. Various radical or oxidation sensitive functional groups are compatible with this protocol, and no anhydrous reagents or solvents are required for the high yields of the benzoylations.

PREPARATION AND CHARACTERIZATION OF MIXED ANHYDRIDES OF O-ACYLARYLCARBOHYDROXIMIC ACID

A number of N,O-diacylhydroxylamines have been prepared by the reaction of potassium salts of hydroxamic acids with a variety of acylating agents which include: benzoyl, p-nitrobenzoyl, anisoyl, p-chlorobenzoyl and lauroyl chlorides in dioxane under reflu