613-70-7

Basic information

• Product Name: 2-METHOXYPHENYL ACETATE
• Synonyms: O-ACETYLGUAIACOL;2-methoxy-phenoacetate;Eucol;o-Acetoxyanisole;o-Anisyl acetate;Phenol, o-methoxy-, acetate;Phenol,2-methoxy-,acetate;2-METHOXYPHENYL ACETATE 98+%
• CAS NO: 613-70-7
• Molecular Formula: C₉H₁₀O₃
• Molecular Weight: 166.17
• EINECS: 210-350-8
• Product Categories: Aromatic Esters
• Mol File: 613-70-7.mol
• Article Data: 61

Chemical Properties

• Melting Point: 31.5°C
• Boiling Point: 122-124 °C18 mm Hg(lit.)
• Flash Point: >230 °F
• Appearance: /
• Density: 1.129 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.0421mmHg at 25°C
• Refractive Index: n20/D 1.514(lit.)
• CAS DataBase Reference: 2-METHOXYPHENYL ACETATE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-METHOXYPHENYL ACETATE(613-70-7)
• EPA Substance Registry System: 2-METHOXYPHENYL ACETATE(613-70-7)

Safety Data

• WGK Germany: 3
• HazardClass: IRRITANT
• Hazardous Substances Data: 613-70-7(Hazardous Substances Data)

Usage

Description

Guaiacyl acetate has an odor similar to that of guaiacol. It may be synthesized from guaiacol and excess acetic anhydride in the presence of trace amounts of H2S04.

Chemical Properties

Guaiacyl acetate has an odor similar to that of guaiacol.

Preparation

From guaiacol and excess acetic anhydride in the presence of trace amounts of H2SO4.

Aroma threshold values

Aroma characteristics at 5.0%: phenolic, guaiacol, smoky and harm-like with a woody, vanilla nuance.

Taste threshold values

Taste characteristics at 50 ppm: woody, guaiacol, smoky, astringent and phenolic with vanillin and couma- rin nuances.

InChI:InChI=1S/C9H10O3/c1-7(10)12-9-6-4-3-5-8(9)11-2/h3-6H,1-2H3

Upstream product

• 47589-95-7 boric acid tris-(2-methoxy-phenyl ester) 
• 108-24-7 acetic anhydride 
• 90-05-1 2-methoxy-phenol 
• 321-28-8 1-fluoro-2-methoxybenzene 
• 127-08-2 potassium acetate 
• 58343-58-1 9,10-dihydro-9,10-dihydroxyanthracene 
• 36382-85-1 2-Methoxy-4-[2-(2-methoxy-phenoxy)-prop-(Z)-ylidene]-cyclohexa-2,5-dienone 
• 100-66-3 methoxybenzene 
• 112488-49-0 2,2,3,3-tetramethoxycyclohepta-4,6-dienone 
• 75-36-5 acetyl chloride 
• 7664-93-9 sulfuric acid 
• 374568-00-0 carbazic acid-(2-methoxy-phenyl ester) 
• 579-74-8 2-Methoxyacetophenone 
• 150-76-5 4-methoxy-phenol 

Downstream Products

• 498-02-2 1-(3-methoxy-4-hydroxyphenyl)ethanone 
• 1197-09-7 1-(3,4-dihydroxyphenyl)ethan-1-one 
• 53606-41-0 2-methoxy-5-nitrophenyl acetate 
• 6100-74-9 3-hydroxy-4-methoxyacetophenone 
• 703-98-0 1-(2-hydroxy-3-methoxyphenyl)ethanone 
• 900152-54-7 methyl 4-bromo-5-{3-[tert-butyl(dimethyl)silyloxy]-4-methoxyphenyl}-1-(4-methoxybenzyl)-1H-pyrrole-2-carboxylate 
• 900152-46-7 4-benzo[1,3]dioxol-5-yl-5-(3-hydroxy-4-methoxy-phenyl)-1-(4-methoxy-benzyl)-1H-pyrrole-2-carboxylic acid methyl ester 
• 900152-42-3 4-(3-hydroxy-4-methoxy-phenyl)-1-(4-methoxy-benzyl)-5-(3,4,5-trimethoxy-phenyl)-1H-pyrrole-2-carboxylic acid methyl ester 
• 900152-44-5 5-(3-hydroxy-4-methoxy-phenyl)-1-(4-methoxy-benzyl)-4-(3,4,5-trimethoxy-phenyl)-1H-pyrrole-2-carboxylic acid methyl ester 
• 160257-85-2 5-iodo-2-methoxyphenol 
• 1941-09-9 5-allyl-2-methoxyphenyl acetate 
• 1357013-33-2 (R)-3-(3-(cyclopentyloxy)-4-methoxyphenyl)-5-phenylpent-4-ynoic acid 

Relevant articles and documents

Total Synthesis of the Ambigols: A Cyanobacterial Class of Polyhalogenated Natural Products

The first total synthesis of all members of the cyanobacterial natural product class of the ambigols is described. Key steps of the synthetic strategy are the formation of sterically demanding mono- and bis-iodonium salts to install the required biaryl ether structural elements and Suzuki cross-coupling giving straightforward access to the biaryl bonds. The synthetic methods are also utilized to construct unnatural or hypothetical ambigols that are still awaiting discovery from Nature.

Solvent-free Acetylation Procedure

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Preparation method of plant growth regulation compound sodium nitrophenolate

The invention relates to the field of preparation of agricultural auxiliaries, in particular to a preparation method of plant growth regulation compound sodium nitrophenolate. According to the invention, acetyl chloride is adopted to replace acetic anhydride which is a precursor to serve as a protecting group for hydroxyl acetylation, so that the acquisition difficulty of process raw materials is reduced, and the production cost of 5-nitroguaiacol sodium salt is controlled; and besides, a phase transfer catalyst is applied to the hydrolysis reaction of 5-nitroacetyl guaiacol, so that the hydrolysis of the product can be effectively promoted, the yield of the hydrolysis reaction is greatly improved, and the overall yield of the 5-nitroguaiacol sodium salt is further improved. The prepared 5-nitroguaiacol sodium salt has the advantage of low cost, and as a main effective component of the compound sodium nitrophenolate, the 5-nitroguaiacol sodium salt can improve the market competitiveness of the compound sodium nitrophenolate product, avoid the behavior that the drug effect of the compound sodium nitrophenolate product is reduced due to the fact that the cost of the 5-nitroguaiacol sodium salt is high and the ratio is reduced by bad manufacturers, and make contribution for promoting the benign development of the market.