6712-20-5

Basic information

• Product Name: 4-methoxyphenyl-1,3-dithiolane
• Synonyms: 4-methoxyphenyl-1,3-dithiolane;2-(4-Methoxyphenyl)-1,3-dithiolane;4-Methoxybenzaldehyde (ethane-1,2-diyl)dithioacetal;4-Methoxybenzaldehyde ethane-1,2-diyldithioacetal;p-Anisaldehyde (ethane-1,2-diyl)dithioacetal
• CAS NO: 6712-20-5
• Molecular Formula: C₁₀H₁₂OS₂
• Molecular Weight: 212.33
• Mol File: 6712-20-5.mol
• Article Data: 89

Chemical Properties

• Boiling Point: 348.2°C at 760 mmHg
• Flash Point: 164.4°C
• Appearance: /
• Density: 1.207g/cm³
• Vapor Pressure: 0.000103mmHg at 25°C
• Refractive Index: 1.613
• CAS DataBase Reference: 4-methoxyphenyl-1,3-dithiolane(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methoxyphenyl-1,3-dithiolane(6712-20-5)
• EPA Substance Registry System: 4-methoxyphenyl-1,3-dithiolane(6712-20-5)

Safety Data

• Hazardous Substances Data: 6712-20-5(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H12OS2/c1-11-9-4-2-8(3-5-9)10-12-6-7-13-10/h2-5,10H,6-7H2,1H3

Upstream product

• 2403-50-1 2-(4-methoxyphenyl)-1,3-dioxolane 
• 540-63-6 ethane-1,2-dithiol 
• 100-09-4 4-methoxybenzoic acid 
• 6290-08-0 p-methoxybenzaldehyde neopentyl glycol acetal 
• 555-16-8 4-nitrobenzaldehdye 
• 123-11-5 4-methoxy-benzaldehyde 
• 14202-31-4 4-methoxybenzaldehyde-1,1-diacetate 
• 2183-30-4 3-(1,3-dithiolan-2-ylidene)pentane-2,4-dione 
• 7647-01-0 hydrogenchloride 
• 3717-21-3 (E)-4-methoxybenzaldoxime 
• 22391-03-3 2-(4-methoxyphenyl)-1,3-oxathiolane 
• 2403-58-9 4-methoxybenzaldehyde diethylacetal 
• 65225-59-4 2-ethoxy-[1,3]dithiolane 

Downstream Products

• 76711-42-7 (E)-2-(4-methoxyphenyl)-1-trimethylsilylethene 
• 20849-32-5 phenyl p-methoxybenzenedithiocarboxylate 
• 1822-73-7 phenylthioethylene 
• 78926-14-4 1-(dibromomethyl)-4-methoxybenzene 
• 126454-91-9 (1R,2R)-2-(4-Methoxy-phenyl)-[1,3]dithiolane 1-oxide 
• 126454-94-2 (1S,2S)-2-(4-Methoxy-phenyl)-[1,3]dithiolane 1-oxide 
• 123-11-5 4-methoxy-benzaldehyde 
• 21185-25-1 p-methoxybenzal chloride 
• 88200-30-0 2-(p-methoxyphenyl)-1,3-dithiolan-2-yl cation 
• 100-09-4 4-methoxybenzoic acid 
• 88180-48-7 2-methoxy-2-(p-methoxyphenyl)-1,3-dithiolane 
• 121-98-2 methyl 4-methoxybenzoate 
• 1353761-06-4 2-ethoxy-2-PMP-1,3-dithiolane 
• 1353761-07-5 C₁₀H₁₂O₂⁽¹⁸⁾O 

Relevant articles and documents

PhIO-Mediated oxidative dethioacetalization/dethioketalization under water-free conditions

Treatment of thioacetals and thioketals with iodosobenzene in anhydrous DCM conveniently afforded the corresponding carbonyl compounds in high yields under water-free conditions. The mechanistic studies indicate that this dethioacetalization/dethioketalization process does not need water and the oxygen of the carbonyl products comes from the hypervalent iodine reagent.

Indium-Catalyzed Reductive Dithioacetalization of Carboxylic Acids with Dithiols: Scope, Limitations, and Application to Oxidative Desulfurization

In this study an InI3-TMDS (1,1,3,3-tetramethyldisiloxane) reducing system effectively catalyzed the reductive dithioacetalization of a variety of aromatic and aliphatic carboxylic acids with 1,2-ethanedithiol or 1,3-propanedithiol leading to the one-pot preparation of either 1,3-dithiolane derivatives or a 1,3-dithiane derivative. Also, the intact indium catalyst continuously catalyzed the subsequent oxidative desulfurization of an in situ formed 1,3-dithiolane derivative, which led to the preparation of the corresponding aldehydes.

Mesoporous sBa-15 silica catalyst functionalized with phenylsulfonic acid groups (SbA-15-ph-So3h) as efficient nanocatalyst for chemoselective thioacetalization of carbonyl compounds

In this research a Nano acidic catalyst was prepared and its efficiency on thioacetalization of carbonyl compounds was examined. For this aim we used modified SBA-15 as support, which have been modified by phenolic and sulfonic acid. SBA-15 is a member of