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Tert-butyl glycidyl ether
Cas No: 7665-72-7
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
whmulei cas 7665-72-7 tert-butyl glycidyl ether china supplier
Cas No: 7665-72-7
USD $ 6.0-12.0 / Gram 50 Gram 100000 Kilogram/Day WUHAN MULEI NEW MATERIAL CO., LTD Contact Supplier
tert-Butyl Glycidyl Ether
Cas No: 7665-72-7
No Data 1 Kilogram 20 Metric Ton/Month Henan Allgreen Chemical Co.,Ltd Contact Supplier
tert-Butyl glycidyl ether
Cas No: 7665-72-7
No Data No Data No Data Chemwill Asia Co., Ltd. Contact Supplier
Manufacturer supply CAS 7665-72-7 with best quality
Cas No: 7665-72-7
USD $ 139.0-210.0 / Kilogram 1 Kilogram 1000 Kilogram/Day Zhuozhou Wenxi import and Export Co., Ltd Contact Supplier
Monad Supply tert-Butyl Glycidyl Ether Cas No: 7665-72-7
Cas No: 7665-72-7
USD $ 1.0-3.0 / Gram 10 Gram 1000 Kilogram/Month Wuhan Monad Medicine Tech Co.,LTD Contact Supplier
Oxirane,2-[(1,1-dimethylethoxy)methyl]-
Cas No: 7665-72-7
No Data No Data No Data Shandong Hanjiang Chemical Co., Ltd. Contact Supplier
Tert-butyl Glycidyl Ether
Cas No: 7665-72-7
No Data 2 Kilogram 150 Kilogram/Week Career Henan Chemical Co Contact Supplier
Oxirane,2-[(1,1-dimethylethoxy)methyl]-
Cas No: 7665-72-7
No Data No Data 5 Hangzhou J&H Chemical Co., Ltd. Contact Supplier
Tert-butyl glycidyl ether
Cas No: 7665-72-7
USD $ 100.0-100.0 / Kilogram 1 Kilogram 1-1000 Metric Ton/Month Metric Ton/Day Zibo Hangyu Import&Export Co., Ltd Contact Supplier

7665-72-7 Usage

Air & Water Reactions

Highly flammable. Ethers tend to form unstable peroxides when exposed to oxygen. Ethyl, isobutyl, ethyl tert-butyl, and ethyl tert-pentyl ether are particularly hazardous in this respect. Ether peroxides can sometimes be observed as clear crystals deposited on containers or along the surface of the liquid. Water soluble.

Reactivity Profile

TERT-BUTYL GLYCIDYL ETHER, an ether, can act as a base. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.

General Description

Clear colorless liquid.

Fire Hazard

TERT-BUTYL GLYCIDYL ETHER is combustible.
InChI:InChI=1/C7H14O2/c1-7(2,3)9-5-6-4-8-6/h6H,4-5H2,1-3H3

7665-72-7 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Aldrich (251712)  tert-Butylglycidylether  99% 7665-72-7 251712-100ML 339.30CNY Detail

7665-72-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-Tert-Butoxy-2,3-Epoxypropane

1.2 Other means of identification

Product number -
Other names Oxirane, [(1,1-dimethylethoxy)methyl]-

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:7665-72-7 SDS

7665-72-7Synthetic route

1-chloro-3-tert-butoxy-2-propanol
22576-65-4

1-chloro-3-tert-butoxy-2-propanol

t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

Conditions
ConditionsYield
With sodium hydroxide at 5℃; for 1h;70%
With sodium hydroxide In hexane at 60℃; for 2h;61.5%
epichlorohydrin
106-89-8

epichlorohydrin

tert-butyl alcohol
75-65-0

tert-butyl alcohol

t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

Conditions
ConditionsYield
With diethyl ether; boron trifluoride Behandeln mit wss. Natronlauge;
With tin(IV) chloride at 90 - 100℃; for 0.333333h;
allyl tert-butyl ether
1471-04-1

allyl tert-butyl ether

t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

Conditions
ConditionsYield
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 45℃; for 48h;
1,2-Epoxy-3-bromopropane
3132-64-7

1,2-Epoxy-3-bromopropane

tert-butyl alcohol
75-65-0

tert-butyl alcohol

t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

Conditions
ConditionsYield
With boron trifluoride In diethyl ether at 50 - 55℃;
t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

aniline
62-53-3

aniline

1-tert-butoxy-3-phenylamino-propan-2-ol

1-tert-butoxy-3-phenylamino-propan-2-ol

Conditions
ConditionsYield
With zirconium(IV) chloride at 20℃; for 0.25h;100%
With lithium bromide at 20℃; for 5h;100%
silica gel at 20℃; for 3h;100%
t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

(S)-2-(hydroxymethyl)piperazine-1-carboxylic acid tert-butyl ester
1030377-21-9

(S)-2-(hydroxymethyl)piperazine-1-carboxylic acid tert-butyl ester

(2S)-tert-butyl 4-(3-(tert-butoxy)-2-hydroxypropyl)-2-(hydroxymethyl)piperazine-1-carboxylate

(2S)-tert-butyl 4-(3-(tert-butoxy)-2-hydroxypropyl)-2-(hydroxymethyl)piperazine-1-carboxylate

Conditions
ConditionsYield
In ethanol at 120℃; for 0.5h; Microwave irradiation;100%
t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

carbon dioxide
124-38-9

carbon dioxide

4-[(1,1-dimethylethoxy)methyl]-1,3-dioxolan-2-one
84137-72-4

4-[(1,1-dimethylethoxy)methyl]-1,3-dioxolan-2-one

Conditions
ConditionsYield
With tri-n-butyl(2-hydroxyethyl)ammonium iodide In neat (no solvent) at 45℃; under 7500.75 Torr; for 18h; Temperature; Pressure; Autoclave;99%
With 18-crown-6 ether; calcium iodide In neat (no solvent) at 23℃; under 760.051 Torr; for 24h; Catalytic behavior; Reagent/catalyst; Temperature; Pressure;99%
With calcium iodide In neat (no solvent) at 25℃; under 7500.75 Torr; for 24h;99%
t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

1-tert-butoxy-3-iodo-propan-2-ol

1-tert-butoxy-3-iodo-propan-2-ol

Conditions
ConditionsYield
With lithium iodide; 1-hexyl-3-methylimidazolium perchlorate at 25℃; for 1h;98%
With iodine; 5,15,10,20-tetraphenylporphyrin In dichloromethane at 20℃; for 5.8h; regioselective reaction;77%
t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

acetone
67-64-1

acetone

4-(tert-butoxymethyl)-2,2-dimethyl-1,3-dioxolane
122977-52-0

4-(tert-butoxymethyl)-2,2-dimethyl-1,3-dioxolane

Conditions
ConditionsYield
With Cr-pillared montmorillonite for 4h; Reflux;97%
With FeOx-pillared bentonite at 60℃; for 2h;63%
With FeOx-pillared bentonite at 60℃; for 2h;63 %Chromat.
t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

ethane-1,2-dithiol
540-63-6

ethane-1,2-dithiol

1-(tert-butoxy)-3-[(2-[3-(tert-butoxy)-2-hydroxypropyl]sulfanylethyl)sulfanyl]-2-propanol

1-(tert-butoxy)-3-[(2-[3-(tert-butoxy)-2-hydroxypropyl]sulfanylethyl)sulfanyl]-2-propanol

Conditions
ConditionsYield
With potassium carbonate for 3h; Heating;96%
N-benzyl-trimethylammonium hydroxide
With potassium carbonate In water Reflux;
t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

1-(tert-butoxy)pent-4-en-2-ol

1-(tert-butoxy)pent-4-en-2-ol

Conditions
ConditionsYield
With hydrogenchloride; methanol; copper(I) bromide dimethylsulfide complex; triphenylphosphine In tetrahydrofuran; water at 0℃; for 8h; Inert atmosphere; Flow reactor; regioselective reaction;96%
t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

pivaloyl chloride
3282-30-2

pivaloyl chloride

C12H23ClO3

C12H23ClO3

Conditions
ConditionsYield
With iron(III) chloride In neat (no solvent) at 20℃; for 0.0833333h; regiospecific reaction;95%
t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

2-Chloroaniline
95-51-2

2-Chloroaniline

1-tert-butoxy-3-(2-chloro-phenylamino)-propan-2-ol

1-tert-butoxy-3-(2-chloro-phenylamino)-propan-2-ol

Conditions
ConditionsYield
With aluminium(III) triflate In toluene at 100℃; for 5h;94%
With BiCl6(3-)*2C4H10N2*ClH*3H(1+)*H2O at 20℃; for 0.15h; Neat (no solvent); regioselective reaction;86%
t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

1-Bromo-3-tert-butoxy-propan-2-ol

1-Bromo-3-tert-butoxy-propan-2-ol

Conditions
ConditionsYield
With lithium bromide; 1-hexyl-3-methylimidazolium perchlorate at 25℃; for 1h;92%
With bromine; 5,15,10,20-tetraphenylporphyrin In dichloromethane at 20℃; for 3.5h; regioselective reaction;78%
t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

carbon disulfide
75-15-0

carbon disulfide

5-tert-butoxymethyl-1,3-oxathiolane-2-thione

5-tert-butoxymethyl-1,3-oxathiolane-2-thione

Conditions
ConditionsYield
With lithium tert-butoxide In neat (no solvent) at 20℃; for 5h; stereoselective reaction;92%
With lithium tert-butoxide In neat (no solvent) at 25℃; for 5h; Sealed tube; regioselective reaction;92%
t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

1,2-epithio-3-tert-butoxypropane
107806-76-8

1,2-epithio-3-tert-butoxypropane

Conditions
ConditionsYield
With potassium thioacyanate; but-2-ene-1,4-diylbis(triphenylphosphinium) dichloride In water at 20℃; for 3h; Green chemistry;91%
With sulfuric acid; thiourea In water for 2h; Ambient temperature;75%
With silica gel; 1-methyl-pyrrolidine-2-thione In dichloromethane at 20℃; for 3.5h;62.8%
t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

N-methylaniline
100-61-8

N-methylaniline

1-tert-butoxy-3-(methyl-phenyl-amino)-propan-2-ol

1-tert-butoxy-3-(methyl-phenyl-amino)-propan-2-ol

Conditions
ConditionsYield
With aluminium(III) triflate In toluene at 100℃; for 5h;91%
t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

1-chloro-3-tert-butoxy-2-propanol
22576-65-4

1-chloro-3-tert-butoxy-2-propanol

Conditions
ConditionsYield
With lithium chloride; 1-hexyl-3-methylimidazolium perchlorate at 60℃; for 3h;90%
t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

3-(tert-butoxy)propane-1,2-diol
74338-98-0

3-(tert-butoxy)propane-1,2-diol

Conditions
ConditionsYield
With water at 100℃;90%
t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

p-toluidine
106-49-0

p-toluidine

C14H23NO2
1178176-76-5

C14H23NO2

Conditions
ConditionsYield
With BiCl6(3-)*2C4H10N2*ClH*3H(1+)*H2O at 20℃; for 0.1h; Neat (no solvent); regioselective reaction;89%
t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

acrylic acid n-butyl ester
141-32-2

acrylic acid n-butyl ester

thioacetic acid
507-09-5

thioacetic acid

butyl 3-{[2-(acetyloxy)-3-isopropoxypropyl]sulfanyl}propanoate

butyl 3-{[2-(acetyloxy)-3-isopropoxypropyl]sulfanyl}propanoate

Conditions
ConditionsYield
Stage #1: t-butyl glycidyl ether; tiolacetic acid In neat (no solvent) at 80℃; for 0.5h; Michael Addition;
Stage #2: acrylic acid n-butyl ester With aluminum oxide In neat (no solvent) at 20℃; Michael Addition;
89%
t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

diphenylmethylpiperazine
841-77-0

diphenylmethylpiperazine

1-(4-benzhydrylpiperazin-1-yl)-3-tert-butoxypropan-2-ol
901663-31-8

1-(4-benzhydrylpiperazin-1-yl)-3-tert-butoxypropan-2-ol

Conditions
ConditionsYield
Stage #1: t-butyl glycidyl ether; diphenylmethylpiperazine With aluminium(III) triflate In toluene at 70℃; for 5h;
Stage #2: With sodium hydrogencarbonate In water; toluene regioselective reaction;
88%
t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

phenylacetylene
536-74-3

phenylacetylene

1-(tert-butoxy)-3-(4-phenyl-1H-1,2,3-triazol-1-yl)propan-2-ol

1-(tert-butoxy)-3-(4-phenyl-1H-1,2,3-triazol-1-yl)propan-2-ol

Conditions
ConditionsYield
With sodium azide In water at 70℃; for 3.25h; Catalytic behavior; Sonication; regioselective reaction;88%
t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

4-chloro-aniline
106-47-8

4-chloro-aniline

C13H20ClNO2
1184609-97-9

C13H20ClNO2

Conditions
ConditionsYield
With BiCl6(3-)*2C4H10N2*ClH*3H(1+)*H2O at 20℃; for 0.116667h; Neat (no solvent); regioselective reaction;87%
t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

(3S)-3-(hydroxymethyl)-1-piperazinecarboxylic acid 1,1-dimethylethyl ester
314741-40-7

(3S)-3-(hydroxymethyl)-1-piperazinecarboxylic acid 1,1-dimethylethyl ester

(3S)-tert-butyl 4-(3-(tert-butoxy)-2-hydroxypropyl)-3-(hydroxymethyl)piperazine-1-carboxylate

(3S)-tert-butyl 4-(3-(tert-butoxy)-2-hydroxypropyl)-3-(hydroxymethyl)piperazine-1-carboxylate

Conditions
ConditionsYield
In ethanol at 120℃; for 0.5h; Microwave irradiation;87%
t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

thiobenzoic acid
98-91-9

thiobenzoic acid

acrylic acid n-butyl ester
141-32-2

acrylic acid n-butyl ester

2-[(3-butoxy-3-oxopropyl)sulfanyl]-1-(isopropoxymethyl)ethyl benzoate

2-[(3-butoxy-3-oxopropyl)sulfanyl]-1-(isopropoxymethyl)ethyl benzoate

Conditions
ConditionsYield
Stage #1: t-butyl glycidyl ether; thiobenzoic acid In neat (no solvent) at 80℃; for 0.5h; Michael Addition;
Stage #2: acrylic acid n-butyl ester With aluminum oxide In neat (no solvent) at 20℃; Michael Addition;
87%
t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

C3H6O*CLiN

C3H6O*CLiN

4-(tert-butoxy)-3-hydroxybutanenitrile
141077-80-7

4-(tert-butoxy)-3-hydroxybutanenitrile

Conditions
ConditionsYield
In tetrahydrofuran for 0.25h; Heating;86%
t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

potassium cyanide
151-50-8

potassium cyanide

4-(tert-butoxy)-3-hydroxybutanenitrile
141077-80-7

4-(tert-butoxy)-3-hydroxybutanenitrile

Conditions
ConditionsYield
salcomine In ethylene glycol at 20℃; for 2.5h;85%
t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

C14H20O2

C14H20O2

Conditions
ConditionsYield
With (2-dicyclohexylphosphino-2’,6’-diisopropoxy-1,1‘-biphenyl)[2-(2’-methylamino-1,1’-biphenyl)]palladium(II) methanesulfonate; C11H16O2; sodium acetate In N,N-dimethyl-formamide at 120℃; for 24h; Inert atmosphere; Glovebox;85%
t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

4-methoxy-aniline
104-94-9

4-methoxy-aniline

C14H23NO3
1183330-72-4

C14H23NO3

Conditions
ConditionsYield
With BiCl6(3-)*2C4H10N2*ClH*3H(1+)*H2O at 20℃; for 0.133333h; Neat (no solvent); regioselective reaction;84%
t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

trimethylsilylazide
4648-54-8

trimethylsilylazide

1-azido-2-trimethylsilyloxy-3-t-butoxy propane

1-azido-2-trimethylsilyloxy-3-t-butoxy propane

Conditions
ConditionsYield
aluminum isopropoxide In dichloromethane for 24h; Ambient temperature;82%
aluminum isopropoxide In dichloromethane for 24h; Ambient temperature;82%
t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

Acetanilid
103-84-4

Acetanilid

C15H23NO3

C15H23NO3

Conditions
ConditionsYield
With palladium diacetate; acetic acid at 60℃; regioselective reaction;80%
t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

N-nosylaniline
1576-44-9

N-nosylaniline

1-(tert-butoxy)-3-((4-nitrophenyl)(phenyl)amino)propan-2-ol

1-(tert-butoxy)-3-((4-nitrophenyl)(phenyl)amino)propan-2-ol

Conditions
ConditionsYield
With potassium carbonate In dimethyl sulfoxide at 70℃; for 4h; Smiles Aromatic Rearrangement;80%
t-butyl glycidyl ether
7665-72-7

t-butyl glycidyl ether

p-nitrobenzenesulfonamide
6325-93-5

p-nitrobenzenesulfonamide

1-(tert-butoxy)-3-((4-nitrophenyl)amino)propan-2-ol

1-(tert-butoxy)-3-((4-nitrophenyl)amino)propan-2-ol

Conditions
ConditionsYield
With potassium carbonate In dimethyl sulfoxide at 70℃; for 4h; Smiles Aromatic Rearrangement;79%

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