Catalyst screening for the hydrothiolation of 4-chlorostyrene 1 with thiophenol 2

June 28, 2024

• Title:       

  Catalyst screening for the hydrothiolation of 4-chlorostyrene 1 with thiophenol 2

• Image Source:

  Iron-catalysed Markovnikov hydrothiolation of styrenes

• Mark:

  Table 1

• Associated context:

  The reactions were run at 80℃ after screening more than twenty metal species as triflate or triflimide salts[M(OTf)_n or M(NTf₂)_n, n=1-4], and the corresponding Bronsted acids HOTf and HNTf₂, as catalysts for the above reaction (Table 1).