Enthalpies of solution and partial molar volumes of magnesium perchlorate in alcohols and salt effect of acceleration of the Diels–Alder reaction
-
Add time:08/07/2019 Source:sciencedirect.com
Densities and enthalpies of solution at 25 °C were measured for dilute solutions of magnesium perchlorate (MP) in some alcohols using the Anton Paar DSA 5000M vibrating tube densimeter and differential calorimetric measurements. In all studied solvents the solution of MP was highly exothermic and large solvent volume contraction was observed. Maximum effect was obtained in methanol and ethanol solutions. Acceleration effect of the Diels–Alder reaction of 9,10-dimethylanthracene with acrylonitrile (in medium of acrylonitrile) in the presence of salts LiClO4, Mg(ClO4)2 and GaCl3 was as 18:160:59,000.
We also recommend Trading Suppliers and Manufacturers of Lithium perchlorate trihydrate (cas 13453-78-6). Pls Click Website Link as below: cas 13453-78-6 suppliers
Prev:A nuclear magnetic resonance study of the motion of water molecules and lithium ions in pyroelectric Lithium perchlorate trihydrate (cas 13453-78-6)
Next:Conductivity and NMR study of composite solid electrolytes based on lithium perchlorate) - 【Back】【Close 】【Print】【Add to favorite 】
- Related Information
- The cause of the rate acceleration by diethyl ether solutions of lithium perchlorate (LPDE) in organic reactions. Application to high pressure synthesis08/11/2019
- On the reaction between molten lithium perchlorate and chromium(III) oxide08/10/2019
- The influence of some transition and inner transition metal oxides on the thermal decomposition of molten lithium perchlorate08/09/2019
- Conductivity and NMR study of composite solid electrolytes based on lithium perchlorate08/08/2019
- A nuclear magnetic resonance study of the motion of water molecules and lithium ions in pyroelectric Lithium perchlorate trihydrate (cas 13453-78-6)08/06/2019
- Spectroscopic and structural studies of di-ureasils doped with lithium perchlorate08/05/2019
- Effect of the microsctructure and lithium-ion content in poly[(vinylidene fluoride)-co-trifluoroethylene]/Lithium perchlorate trihydrate (cas 13453-78-6) composite membranes for battery applications08/04/2019
-
Health and Chemical more >