Original articleMultifunctionalization of Cyanuric chloride (cas 108-77-0) for the stepwise synthesis of potential multimodal imaging chemical entities
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Add time:08/19/2019 Source:sciencedirect.com
We report a synthetic strategy to combine different moieties in a single structure using Cyanuric chloride (cas 108-77-0) (2,4,6-trichlorotriazine) as a starting platform for preparing potential bioimaging agents. This reacted with macrocycles of the porphyrin family and DOTA type metal chelators through mono-, di- and tri- substitution of its chlorine atoms by appropriate nucleophiles, controlling the stepwise by temperature, to produce a system that opens the potential for biomedicinal applications. Porphyrins were chosen as one of the sensing arms, based on their rich structural chemistry, and excellent photophysical properties, while DO3A was used since it can form a versatile aminopropionate functionalized metal ion chelator. All new compounds were fully characterized, both spectroscopically and photophysically.
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