One-pot synthesis of triazole-fused isoindoles from o-alkynylbenzaldehydes and trimethylsilyl azide
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Add time:08/27/2019 Source:sciencedirect.com
An efficient one-pot synthesis of 1,2,3-triazole-fused isoindoles from o-alkynylbenzaldehydes and trimethylsilyl azide (TMSN3) is reported. The reaction proceeds through the formation of a diazide intermediate and a subsequent intramolecular azide-alkyne cycloaddition, providing a novel access to a variety of 8-azido-8H-[1,2,3]triazolo[5,1-a]isoindoles in high yields.
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