Thermal degradation of poly(2-methoxyethyl methacrylate)

Add time:09/24/2019    Source:sciencedirect.com

When poly(2-methoxyethyl methacrylate) decomposes thermally at temperatures up to 500°C, two separate reactions occur. The major reaction is depolymerization giving monomer as the only product. The minor reaction is ester decomposition which results in a very small yield of volatile products including carbon monoxide, carbon dioxide, methane, ethylene, isobutene, methyl vinyl ether, methanol and formaldehyde. A mechanism which accounts for all these products has been formulated.

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