Regular paperThermokinetic investigation of Methanesulfonyl chloride (cas 124-63-0)-water system
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Add time:09/09/2019 Source:sciencedirect.com
Thermal analysis of the methanesulfonyl chloride (MSC)-water system reacting under both homogeneous and heterogeneous conditions has been performed by means of adiabatic calorimetry. The enthalpy of solution of methanesulfonyl chloride in water at 298 K (− 112 cal mol−1) and the enthalpy of the hydrolysis reaction (ΔH = − 40.8 kcal mol−1) have been experimentally evaluated. A mathematical model describing the reactive behavior of the MSC-water system under heterogeneous conditions has been developed. The model gives rational criteria for assessment of the safe operating conditions in industrial applications.
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