- Bismuth
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- Bismuth arsphenamine sulfonate
- Bismuth bromide
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- 7787-63-5Bismuthine, iodooxo-(9CI)
- 7787-64-6Bismuthine, triiodo-
- 7787-68-0Sulfuric acid,bismuth(3+) salt (3:2) (8CI,9CI)
- 7787-69-1Cesium bromide (CsBr)
- 7787-70-4Copper bromide (CuBr)
- 7787-71-5Bromine fluoride (BrF3)
- 77877-19-12-Oxazolidinone,4-(1-methylethyl)-3-(1-oxopropyl)-, (4S)-
- 7787-85-1Silane,dichloro(2-chloroethyl)methyl-
- 7787-87-3Silane,(1-chloroethyl)trimethyl-
- 7787-93-1Silane,dichloro(3-chloropropyl)methyl-
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Cas Database |
| Name |
Bismuth trichloride |
EINECS | 232-123-2 |
| CAS No. | 7787-60-2 | Density | 4.75 g/cm3 |
| PSA | 0.00000 | LogP | 2.06850 |
| Solubility | Decomposes in water | Melting Point |
230-232 °C(lit.) |
| Formula | BiCl3 | Boiling Point | 447oC |
| Molecular Weight | 315.339 | Flash Point | 430°C |
| Transport Information | N/A | Appearance | White crystal and crystalline powder |
| Safety | 26-37/39 | Risk Codes | 36/37/38 |
| Molecular Structure |
|
Hazard Symbols |
 Xi
|
| Synonyms |
Bismuthchloride (BiCl3) (6CI,8CI);Bismuth chloride;Bismuthtrichloride (BiCl3);Bismuth(III) chloride;Trichlorobismuth;Trichlorobismuthine;Bismuth trchloride; |
Article Data | 197 |
Bismuth trichloride Synthetic route
| Conditions | Yield |
|---|---|
| byproducts: benzene; heating (CH3)3NHCl with triphenyl bismuth at 130°C (also in presence of ethanol);; | 100% |
| byproducts: benzene; heating (CH3)3NHCl with triphenyl bismuth at 130°C (also in presence of ethanol);; | 100% |
| Conditions | Yield |
|---|---|
| In acetic acid byproducts: H2O; | 100% |
| In acetic acid byproducts: H2O; | 100% |
| In neat (no solvent) volatilization of Bi2O3 in HCl-stream at 130 °C;; | > 99 |
| In neat (no solvent) volatilization of Bi2O3 in HCl-stream at 130 °C;; | > 99 |
| In perchloric acid aq. HClO4; prepn. by dissolving Bi2O3 in 6 M HCl; |
| Conditions | Yield |
|---|---|
| heating Bi with S2Cl2 at 138.6°C, 10 hours;; | 100% |
| addition of S2Cl2 to Bi;; | |
| addition of S2Cl2 to Bi;; |
| Conditions | Yield |
|---|---|
| In melt passing a stream of Cl2/inert gas into molten Bi with formation of volatile BiCl3; description of the aparatus given;; | 100% |
| In melt passing a stream of Cl2/inert gas into molten Bi with formation of volatile BiCl3; description of the aparatus given;; | 100% |
| In melt passing a stream of Cl2/inert gas into molten Bi with formation of volatile BiCl3; description of the aparatus given;; | 100% |
- 33397-22-7
tri(naphthalen-1-yl)bismuth
A
- 91-20-3
naphthalene
B
- 642-29-5
1-benzoylnaphthalene
C
- 7787-60-2
bismuth(III) chloride
| Conditions | Yield |
|---|---|
| With aluminium trichloride; benzoic acid In chloroform 5 h reflux, molar ratio Bi(1-C10H7)3:AlCl3:C6H5COOH = 1:1:1; | A 34% B 9.3% C 99% |
| With iron(III) chloride; benzoic acid In chloroform 5 h reflux, molar ratio Bi(1-C10H7)3:FeCl3:C6H5COOH = 1:1:1; | A 44% B 10.2% C 96% |
| Conditions | Yield |
|---|---|
| With benzoic acid In chloroform molar ratio Bi(1-C10H7)3:C6H5COOH = 1:1; | A 49.1% B 98.4% |
| With AlCl3 or FeCl3 In chloroform reflux; | A 36-46 B >97 |
- 13453-32-2
thallium (III) chloride
- 93690-72-3
tri(isopropenyl)bismuthane
B
- 7787-60-2
bismuth(III) chloride
| Conditions | Yield |
|---|---|
| In diethyl ether at -40°C; | A 98% B n/a |
| Conditions | Yield |
|---|---|
| In ethanol High Pressure; mixing Bi2S3 and CuCl in ethanol, heating at 120°C for 2 d in autoclave, cooling to room temp.; filtration, washing with dild. HCl, water, ammonia, ethanol, drying in vac.; | A 82% B n/a |
- 7647-01-0
hydrogenchloride
- 7440-69-9
bismuth
- 10241-05-1
molybdenum(V) chloride
B
- 7787-60-2
bismuth(III) chloride
| Conditions | Yield |
|---|---|
| In neat (no solvent) ampule with MoCl5 and Bi was heated to 230°C (2 h), to 350°C (2 h) and kept at 350°C for 12 h, cooled, homogenized and heated to 350°C (3 h) , reoriented and heated at 350°C for 24 h, cooled, treated with 12 M HCl; recrystn.; X-ray diffraction; | A 80% B n/a |
| In neat (no solvent) ampule with MoCl5 and Bi in the end reaction chamber was heated to 230°C over 2 h and to 350°C over 2 h, ampule wasrepositioned toremove BiCl3 by sublimation and heated at 350°C for 24 h, cooled , treated with 12 M HCl and heated; recrystn.; X-ray diffraction; | A 58% B n/a |
| Conditions | Yield |
|---|---|
| In melt ardent reaction of powdered Bi with molten ICl;; | 60% |
| In melt ardent reaction of powdered Bi with molten ICl;; | 60% |
| In melt addition of powdered Bi to molten ICl under reflux with formation of BiCl3;; reaction of 60 % of Bi;; | |
| In melt addition of powdered Bi to molten ICl under reflux with formation of BiCl3;; reaction of 60 % of Bi;; |
Bismuth trichloride Specification
The Bismuthine, trichloro-, with the CAS registry number 7787-60-2 and EINECS registry number 232-123-2, has the systematic name of bismuth(+3) trihydride cation trichloride. It is a kind of white crystal and crystalline powder, and belongs to the following product categories: Inorganics; Bismuth Salts; BismuthMetal and Ceramic Science; Catalysis and Inorganic Chemistry; Chemical Synthesis; Crystal Grade Inorganics; Salts; Bismuth SaltsEssential Chemicals; Reagent Grade; Routine Reagents. And the molecular formula of the chemical is BiCl3.
The characteristics of Bismuthine, trichloro- are as followings: (1)H-Bond Donor 0; (2)H-Bond Acceptor 0 ; (3)Rotatable Bond Count 0; (4)Exact Mass 313.886941; (5)MonoIsotopic Mass 313.886941; (6)Topological Polar Surface Area 0; (7)Heavy Atom Count 4; (8)Formal Charge 0; (9)Complexity 8; (10)Isotope Atom Count 0; (11)Defined Atom StereoCenter Count 0; (12)Undefined Atom StereoCenter Count 0; (13)Defined Bond StereoCenter Count 0; (14)Undefined Bond StereoCenter Count ; (15)Covalently-Bonded Unit Count 1.
You should be cautious while dealing with this chemical. It irritates to eyes, respiratory system and skin. Therefore, you had better take the following instructions: Wear suitable protective gloves and eye/face protection, and if in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice.
Addtionally, the following datas could be converted into the molecular structure:
(1)SMILES: [Cl-].[Cl-].[Cl-].[BiH3+3]
(2InChI: InChI=1/Bi.3ClH.3H/h;3*1H;;;/q+3;;;;;;/p-3/rBiH3.3ClH/h1H3;3*1H/q+3;;;/p-3
(3)InChIKey: QJWNFCZARGUHFM-YRLNYOAXAG
The toxicity data is as follows:
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| mouse | LD50 | oral | 2250mg/kg (2250mg/kg) | Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 30(6), Pg. 16, 1986. | |
| rat | LD50 | oral | 3334mg/kg (3334mg/kg) | Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 30(6), Pg. 16, 1986. |
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