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3-BROMO-1,1,1-TRIFLUOROPROPANE is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 460-32-2 Structure
  • Basic information

    1. Product Name: 3-BROMO-1,1,1-TRIFLUOROPROPANE
    2. Synonyms: 3-BROMO-1,1,1-TRIFLUOROPROPANE;3,3,3-TRIFLUOROPROPYL BROMIDE;1-BROMO-3,3,3-TRIFLUOROPROPANE;TIMTEC-BB SBB008495;3-BROMO-1 1 1-TRIFLUOROPROPANE 98%;1-Bromo-3,3,3-trifluoropropane 99%;1-Bromo-3,3,3-trifluoropropane99%;3-Bromo-1,1,1-trifluoropropane,98%
    3. CAS NO:460-32-2
    4. Molecular Formula: C3H4BrF3
    5. Molecular Weight: 176.96
    6. EINECS: 1592732-453-0
    7. Product Categories: N/A
    8. Mol File: 460-32-2.mol
  • Chemical Properties

    1. Melting Point: 62-63℃
    2. Boiling Point: 62 °C
    3. Flash Point: >110°C
    4. Appearance: clear colourless liquid
    5. Density: 1.662
    6. Vapor Pressure: 175mmHg at 25°C
    7. Refractive Index: 1.362-1.364
    8. Storage Temp.: N/A
    9. Solubility: N/A
    10. CAS DataBase Reference: 3-BROMO-1,1,1-TRIFLUOROPROPANE(CAS DataBase Reference)
    11. NIST Chemistry Reference: 3-BROMO-1,1,1-TRIFLUOROPROPANE(460-32-2)
    12. EPA Substance Registry System: 3-BROMO-1,1,1-TRIFLUOROPROPANE(460-32-2)
  • Safety Data

    1. Hazard Codes: N-Xi,Xi,N
    2. Statements: 59-36/37/38
    3. Safety Statements: 59-37/39-26
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: IRRITANT, OZONE DEPLETER
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 460-32-2(Hazardous Substances Data)

460-32-2 Usage

Chemical Properties

CLEAR COLOURLESS LIQUID

Check Digit Verification of cas no

The CAS Registry Mumber 460-32-2 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 4,6 and 0 respectively; the second part has 2 digits, 3 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 460-32:
(5*4)+(4*6)+(3*0)+(2*3)+(1*2)=52
52 % 10 = 2
So 460-32-2 is a valid CAS Registry Number.
InChI:InChI=1/C3H4BrF3/c4-2-1-3(5,6)7/h1-2H2

460-32-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name 3-BROMO-1,1,1-TRIFLUOROPROPANE

1.2 Other means of identification

Product number -
Other names 3,3,3-trifluoropropyl bromide

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:460-32-2 SDS

460-32-2Relevant articles and documents

Deoxofluorination of Aliphatic Carboxylic Acids: A Route to Trifluoromethyl-Substituted Derivatives

Bugera, Maksym,Trofymchuk, Serhii,Tarasenko, Karen,Zaporozhets, Olga,Pustovit, Yurii,Mykhailiuk, Pavel K.

, p. 16105 - 16115 (2019/12/24)

A practical method for the synthesis of functionalized aliphatic trifluoromethyl-substituted derivatives from aliphatic acids is developed. The transformation proceeds with sulfur tetrafluoride in the presence of water as a key additive. Compared to previous methods, the reaction gives products with full retention of stereo- and absolute configuration of chiral centers.

Design of fluorinated 5-HT4R antagonists: Influence of the basicity and lipophilicity toward the 5-HT4R binding affinities

Fontenelle, Clement Q.,Wang, Zhong,Fossey, Christine,Cailly, Thomas,Linclau, Bruno,Fabis, Frederic

, p. 7529 - 7538 (2013/11/19)

Analogues of potent 5-HT4R antagonists possessing a fluorinated N-alkyl chain have been synthesized in order to investigate the effect of the resulting change in basicity and lipophilicity on the affinity and selectivity profile. We demonstrate that for this series, the affinity is decreased with decreased basicity of the piperidine's nitrogen atom. In contrast, the resulting increase in lipophilicity has minimal impact on binding affinity and selectivity. 3,3,3-Trifluoropropyl and 4,4,4-trifluorobutyl derivatives 6d and 6e have shown to bind to the 5-HT4R while maintaining their pharmacological profile and selectivity toward other 5-HT receptors.

KrF laser induced telomerization of bromides with olefins. Part 1. Self-inhibition and kinetic analysis

Linyang,Fuss,Kompa

, p. 867 - 874 (2007/10/02)

The chain reaction of several organic bromides with olefins was induced by a KrF laser. In all cases we found a self-inhibition, leading to a termination of first order in the radical concentration. There is indirect evidence that it is due to molecular bromine, accumulated during the reaction in spite of the presence of olefins. It has not been noticed previously. We show that kinetic analysis is easy also for pulsed excitation, and the example CF3Br + C2H4 is studied in detail. We found rate constants for CF3 + C2H4 → CF3C2H4 (7.2·109 cm3 mol-1 s-1; this is in between two previous values) and for CF3C2H4 + CF3Br → CF3C2H4Br + CF3(1.2·109 cm3 mol-1 s-1) as well as preliminary values for some other reactions.

Structural Effects on the Transition States of Imine-Forming Eliminations in N-Substituted O-(Arylsulfonyl)hydroxylamines

Hoffman, Robert V.,Shankweiler, Jean M.

, p. 4019 - 4022 (2007/10/02)

A series of amines with various alkyl and aryl substituents at C-1 were converted to the corresponding N-(arylsulfonoxy)amines, which served as precursors for base-promoted, imine-forming elimination.By varying the bases used to promote the elimination and by varying the leaving groups attached to nitrogen, the Broensted parameters β and βlgCH3 were determined.These were used to locate the transition state on the More O'Ferrall-Jencks energy surface for elimination.Substituents were found to influence the structure of the activated complex markedly.Resonance effects were most important, while inductive effects had little influence .

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