14986-21-1Relevant articles and documents
DIRECT MASS SPECTROMETRIC IDENTIFICATION OF SILICON OXYCHLORIDE COMPOUNDS.
Marra,Kreidler,Jacobson,Fox
, p. 1571 - 1574 (1988)
Silicon oxychloride compounds formed during the high temperature reaction of Si and SiC with Cl//2/O//2 mixtures at 930 degree and 950 degree C have been directly observed with an atmospheric pressure mass spectrometer sampling system. Molecules with the formulas Si//2OCl//6 and Si//3OCl//8 have been identified. These compounds are very likely formed by a gas phase reaction between the oxygen gas in the system and silicon tetrachloride which is produced by chlorination of the silicon-based material.
METHOD OF MAKING A HALOSILOXANE
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Paragraph 0041; 0051; 0052, (2019/01/06)
A method of producing a halosiloxane, the method comprising: i) combining water, a halosilane, and a first solvent to form a reaction mixture, ii) partially hydrolyzing and condensing the halosilane to form a reaction product mixture comprising the halosiloxane, the solvent, unreacted halosilane, and hydrogen halide, iii) adding a second solent, where the second solent has a boiling point the boiling point of the halosiloxane, to the reaction mixture in i) or to the reaction product mixture in ii), and iv) recovering the halosiloxane from the reaction product mixture.
A New Route to Linear and Cyclic Perchlorosiloxanes
Basenko, S. V.,Gebel', I. A.,Voronkov, M. G.,Klyba, L. V.,Mirskov, R. G.
, p. 314 - 315 (2008/10/09)
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