Welcome to LookChem.com Sign In|Join Free

Cas Database

1826-67-1

1826-67-1

Identification

Synonyms:Magnesium,bromovinyl- (7CI,8CI);Vinylmagnesium bromide (6CI);Bromovinylmagnesium;Ethenylmagnesium bromide;Norman reagent;

Post Buying Request Now
Entrust LookChem procurement to find high-quality suppliers faster

Safety information and MSDS view more

  • Pictogram(s):FlammableF, CorrosiveC

  • Hazard Codes:F,C

  • Signal Word:Danger

  • Hazard Statement:H260 In contact with water releases flammable gases which may ignite spontaneouslyH314 Causes severe skin burns and eye damage

  • First-aid measures: General adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

  • Fire-fighting measures: Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus for firefighting if necessary.

  • Accidental release measures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

  • Handling and storage: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

  • Exposure controls/personal protection:Occupational Exposure limit valuesBiological limit values Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/face protection Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Respiratory protection Wear dust mask when handling large quantities. Thermal hazards

Supplier and reference price

  • Manufacture/Brand
  • Product Description
  • Packaging
  • Price
  • Delivery
  • Purchase
  • Manufacture/Brand:TCI Chemical
  • Product Description:Vinylmagnesium Bromide (14% in Tetrahydrofuran, ca. 1mol/L)
  • Packaging:100g
  • Price:$ 81
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Vinylmagnesium bromide solution 1.0 M in THF
  • Packaging:200ml
  • Price:$ 174
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Vinylmagnesium bromide solution 1.0 M in THF
  • Packaging:800ml
  • Price:$ 153
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Vinylmagnesium bromide solution 1.0 M in THF
  • Packaging:4x100ml
  • Price:$ 151
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Vinylmagnesium bromide solution 1.0 M in THF
  • Packaging:100ml
  • Price:$ 51.3
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Vinylmagnesium bromide solution 1.0?M in THF
  • Packaging:18 L
  • Price:$ 1870
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Vinylmagnesium bromide solution 1.0 M in THF
  • Packaging:18l-kl
  • Price:$ 1770
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Vinylmagnesium bromide solution 1.0 M in THF
  • Packaging:1.8l
  • Price:$ 534
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:American Custom Chemicals Corporation
  • Product Description:VINYLMAGNESIUM BROMIDE 95.00%
  • Packaging:100G
  • Price:$ 2485.53
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:American Custom Chemicals Corporation
  • Product Description:VINYLMAGNESIUM BROMIDE 95.00%
  • Packaging:100ML
  • Price:$ 235
  • Delivery:In stock
  • Buy Now

Relevant articles and documentsAll total 13 Articles be found

Reimschuessel

, p. 2256 (1960)

Formal synthesis of dysiherbaine

Rao, Maddimsetti Venkateswara,Naresh, Annavareddi,Saketh, Gudipati,Rao, Batchu Venkateswara

supporting information, p. 6931 - 6933 (2019/04/10)

A formal synthesis of dysiherbaine was achieved from D-mannitol using Grignard addition on chiral imine, RCM and Michael addition as key steps.

PYRIDOPYRIMIDINE OR NAPHTHYRIDINE DERIVATIVE

-

Page/Page column 33, (2010/02/07)

A pyridopyrimidine or a naphthyridine derivative of the formula (I): wherein R1 is an optionally substituted nitrogen-containing heterocyclic group, etc.; R2 is H or a lower alkyl group; R3 is H or an optionally substitute

Synthesis of coenzyme Q10, ubiquinone

-

, (2008/06/13)

Processes for the stereospecific synthesis of coenzyme Q10, ubiquinone, are disclosed; a semi synthetic procedure using solanesol derived from tobacco waste as the starting material. The process of the invention results in high yields of isometrically use

Diphenyl ether derivatives

-

, (2008/06/13)

-

Aromatic compounds

-

, (2008/06/13)

-

Process route upstream and downstream products

Process route

Vinyl bromide
593-60-2,25951-54-6

Vinyl bromide

vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

Conditions
Conditions Yield
With magnesium; In tetrahydrofuran; diethyl ether; at 0 ℃;
With iodine; magnesium; In tetrahydrofuran; for 0.5h; Ambient temperature;
With magnesium; In tetrahydrofuran;
With iodine; magnesium; In tetrahydrofuran; diethyl ether; 50-60 deg C, 30 min; 70 deg C, 30 min;
With magnesium; iodine; methyl iodide; In tetrahydrofuran; at 50 - 60 ℃; for 1h;
Vinyl bromide; With magnesium; iodine; In tetrahydrofuran; Heating / reflux;
Vinyl bromide; In tetrahydrofuran; Heating / reflux;
With magnesium; In tetrahydrofuran;
Vinyl bromide
593-60-2,25951-54-6

Vinyl bromide

vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

Conditions
Conditions Yield
In tetrahydrofuran;
vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

Conditions
Conditions Yield
3-(4-fluoro-3-benzylphenyl)prop-2-en-1-yl triphenyl phosphonium chloride
115466-91-6

3-(4-fluoro-3-benzylphenyl)prop-2-en-1-yl triphenyl phosphonium chloride

vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

Conditions
Conditions Yield
Conditions
Conditions Yield
With C70H40Cl2F68N2O6Pd2; In tetrahydrofuran; at 100 ℃; for 0.0125h; Microwave irradiation;
86%
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; In tetrahydrofuran; for 0.166667h; Yield given; further catalyst;
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; In tetrahydrofuran; for 0.0833333h;
95 % Chromat.
vinyl magnesium bromide; With (triphenylphosphine)gold(I) chloride; In tetrahydrofuran; at -20 - -5 ℃; Inert atmosphere;
iodobenzene; With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; In acetonitrile; at 20 ℃; Inert atmosphere;
5-bromo-2-thiophencarboxaldehyde
4701-17-1

5-bromo-2-thiophencarboxaldehyde

manganese dioxide
1313-13-9

manganese dioxide

aqueous NH4 Cl

aqueous NH4 Cl

vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

2-bromothiophene
1003-09-4

2-bromothiophene

Conditions
Conditions Yield
In tetrahydrofuran; dichloromethane;
2-methylchlorobenzene
95-49-8

2-methylchlorobenzene

vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

1-methyl-2-vinyl-benzene
611-15-4

1-methyl-2-vinyl-benzene

Conditions
Conditions Yield
vinyl magnesium bromide; With zinc(II) chloride; In tetrahydrofuran; 1-methyl-pyrrolidin-2-one; at 60 ℃; for 0.333333h;
2-methylchlorobenzene; ((Cy2POH)2PdCl)2; In 1-methyl-pyrrolidin-2-one; at 50 ℃; for 3h; Further stages.;
84%
2-methylphenyl bromide
95-46-5

2-methylphenyl bromide

vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

1-methyl-2-vinyl-benzene
611-15-4

1-methyl-2-vinyl-benzene

Conditions
Conditions Yield
vinyl magnesium bromide; With zinc(II) chloride; In tetrahydrofuran; 1-methyl-pyrrolidin-2-one; at 60 ℃; for 0.333333h;
2-methylphenyl bromide; ((Cy2POH)2PdCl)2; In 1-methyl-pyrrolidin-2-one; at 50 ℃; for 1h; Further stages.;
91%
ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

1-methyl-2-vinyl-benzene
611-15-4

1-methyl-2-vinyl-benzene

Conditions
Conditions Yield
vinyl magnesium bromide; With (triphenylphosphine)gold(I) chloride; In tetrahydrofuran; at -20 - -5 ℃; Inert atmosphere;
ortho-methylphenyl iodide; With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; In acetonitrile; at 20 ℃; Inert atmosphere;
Conditions
Conditions Yield
With C70H40Cl2F68N2O6Pd2; In tetrahydrofuran; at 100 ℃; for 0.0166667h; Microwave irradiation;
86%

Global suppliers and manufacturers

Global( 114) Suppliers
  • Company Name
  • Business Type
  • Contact Tel
  • Emails
  • Main Products
  • Country
  • Simagchem Corporation
  • Business Type:Manufacturers
  • Contact Tel:+86-592-2680277
  • Emails:sale@simagchem.com
  • Main Products:110
  • Country:China (Mainland)
  • Amadis Chemical Co., Ltd.
  • Business Type:Lab/Research institutions
  • Contact Tel:86-571-89925085
  • Emails:sales@amadischem.com
  • Main Products:29
  • Country:China (Mainland)
  • Shanghai Upbio Tech Co.,Ltd
  • Business Type:Lab/Research institutions
  • Contact Tel:+86-21-52196435
  • Emails:upbiocn@hotmail.com
  • Main Products:88
  • Country:China (Mainland)
  • Chemwill Asia Co., Ltd.
  • Business Type:Manufacturers
  • Contact Tel:021-51086038
  • Emails:sales@chemwill.com
  • Main Products:56
  • Country:China (Mainland)
close
Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 1826-67-1
Post Buying Request Now
close
Remarks: The blank with*must be completed