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855-38-9 Usage

Chemical Properties

White to pale yellow crystalline powder

Uses

Different sources of media describe the Uses of 855-38-9 differently. You can refer to the following data:
1. suzuki reaction
2. Tris(4-methoxyphenyl)phosphine is a useful intermediate employed in organic synthesis and in other chemical processes.

Check Digit Verification of cas no

The CAS Registry Mumber 855-38-9 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 8,5 and 5 respectively; the second part has 2 digits, 3 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 855-38:
(5*8)+(4*5)+(3*5)+(2*3)+(1*8)=89
89 % 10 = 9
So 855-38-9 is a valid CAS Registry Number.
InChI:InChI=1/C21H21O3P/c1-22-16-4-10-19(11-5-16)25(20-12-6-17(23-2)7-13-20)21-14-8-18(24-3)9-15-21/h4-15H,1-3H3

855-38-9 Well-known Company Product Price

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  • TCI America

  • (T0861)  Tris(4-methoxyphenyl)phosphine  >97.0%(T)

  • 855-38-9

  • 5g

  • 760.00CNY

  • Detail
  • TCI America

  • (T0861)  Tris(4-methoxyphenyl)phosphine  >97.0%(T)

  • 855-38-9

  • 25g

  • 1,990.00CNY

  • Detail
  • Alfa Aesar

  • (A15596)  Tris(4-methoxyphenyl)phosphine, 98%   

  • 855-38-9

  • 1g

  • 321.0CNY

  • Detail
  • Alfa Aesar

  • (A15596)  Tris(4-methoxyphenyl)phosphine, 98%   

  • 855-38-9

  • 5g

  • 1282.0CNY

  • Detail
  • Alfa Aesar

  • (A15596)  Tris(4-methoxyphenyl)phosphine, 98%   

  • 855-38-9

  • 25g

  • 3494.0CNY

  • Detail
  • Alfa Aesar

  • (30192)  Tris(4-methoxyphenyl)phosphine, 97+%   

  • 855-38-9

  • 1g

  • 225.0CNY

  • Detail
  • Alfa Aesar

  • (30192)  Tris(4-methoxyphenyl)phosphine, 97+%   

  • 855-38-9

  • 5g

  • 1012.0CNY

  • Detail
  • Aldrich

  • (395102)  Tris(4-methoxyphenyl)phosphine  95%

  • 855-38-9

  • 395102-1G

  • 200.07CNY

  • Detail
  • Aldrich

  • (395102)  Tris(4-methoxyphenyl)phosphine  95%

  • 855-38-9

  • 395102-5G

  • 780.39CNY

  • Detail

855-38-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name Tris(4-methoxyphenyl)phosphine

1.2 Other means of identification

Product number -
Other names TRIS(4-METHOXYPHENYL)PHOSPHINE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:855-38-9 SDS

855-38-9Synthetic route

Tris(4-methoxyphenyl)phosphine oxide
803-17-8

Tris(4-methoxyphenyl)phosphine oxide

P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

Conditions
ConditionsYield
With chloro-trimethyl-silane; tetrabutylammomium bromide; copper; zinc In acetonitrile at 45℃; Electrochemical reaction; Inert atmosphere;93%
With chloro-trimethyl-silane; magnesium at 20℃; for 2h;93%
With oxalyl dichloride; diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate; triethylamine In dichloromethane at 40℃; for 2h; Inert atmosphere;83%
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

Conditions
ConditionsYield
With phosphorus trichloride89%
Stage #1: 1-bromo-4-methoxy-benzene With magnesium In tetrahydrofuran at 42 - 55℃; for 2h;
Stage #2: With phosphorus trichloride In tetrahydrofuran at 25 - 85℃; for 3.5h;
Stage #3: With hydrogenchloride In tetrahydrofuran; water for 1.5h;
75.62%
Stage #1: 1-bromo-4-methoxy-benzene With n-butyllithium In tetrahydrofuran; hexane at -50℃; for 0.5h; Inert atmosphere;
Stage #2: With phosphorus trichloride In tetrahydrofuran; hexane at -50 - -10℃; Inert atmosphere;
55%
(4-methoxyphenyl)zinc(II) bromide
82303-13-7

(4-methoxyphenyl)zinc(II) bromide

P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

Conditions
ConditionsYield
With phosphorus trichloride In acetonitrile at 20℃; for 2h;45%
4-methoxyphenyl magnesium bromide
13139-86-1

4-methoxyphenyl magnesium bromide

P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

Conditions
ConditionsYield
With diethyl ether; hydrogen; phosphorus trichloride
p-methoxyphenyllithium
14774-77-7

p-methoxyphenyllithium

P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

Conditions
ConditionsYield
With phosphorus trichloride at -20℃; Yield given;
(2-quinaldinate)(carbonyl)(P(4-CH3O-C5H4)3)2rhodium(I)
119854-20-5

(2-quinaldinate)(carbonyl)(P(4-CH3O-C5H4)3)2rhodium(I)

(2-quinaldinate)(carbonyl)(P(4-CH3O-C5H4)3)rhodium(I)
119882-07-4

(2-quinaldinate)(carbonyl)(P(4-CH3O-C5H4)3)rhodium(I)

B

P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

Conditions
ConditionsYield
In not given 24 h;
C39H33BF3O3P

C39H33BF3O3P

A

P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

B

tris(4-fluorophenyl)borane
47196-74-7

tris(4-fluorophenyl)borane

Conditions
ConditionsYield
In dichloromethane at 20℃;
C39H33BCl3O3P

C39H33BCl3O3P

A

tris(4-chlorophenyl)borane
28445-30-9

tris(4-chlorophenyl)borane

B

P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

Conditions
ConditionsYield
In dichloromethane at 20℃;
C39H27BF9O3P

C39H27BF9O3P

A

P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

B

tris(2,4,6-trifluorophenyl)borane triethylphosphine oxide

tris(2,4,6-trifluorophenyl)borane triethylphosphine oxide

Conditions
ConditionsYield
In dichloromethane at 20℃;
C39H27BF9O3P

C39H27BF9O3P

A

tris(3,4,5-trifluorophenyl)borane
148892-97-1

tris(3,4,5-trifluorophenyl)borane

B

P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

Conditions
ConditionsYield
In dichloromethane at 20℃;
P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

Tris(4-methoxyphenyl)phosphine oxide
803-17-8

Tris(4-methoxyphenyl)phosphine oxide

Conditions
ConditionsYield
With 4-phenylthioxanthone In methanol at 20℃; under 760.051 Torr; for 0.666667h; Mechanism; Solvent; Irradiation;100%
With potassium permanganate99%
With gold(III) complex supported on cellulose extracted from Carthamus tinctorius immobilized on nanofibrous phosphosilicate; air at 20℃; for 1h; Irradiation;98%
4-tolyl iodide
624-31-7

4-tolyl iodide

P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

Tris-(4-methoxy-phenyl)-p-tolyl-phosphonium; iodide

Tris-(4-methoxy-phenyl)-p-tolyl-phosphonium; iodide

Conditions
ConditionsYield
With palladium diacetate In benzene at 120℃; for 25h;100%
P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

tris(4-methoxyphenyl)phosphine selenide
41398-48-5

tris(4-methoxyphenyl)phosphine selenide

Conditions
ConditionsYield
With selenium In toluene for 6h; Heating;100%
With selenium In toluene at 90℃;97%
With selenium In ethanol Heating;
[FeI(CO)2(η5-C5H4CH3)]

[FeI(CO)2(η5-C5H4CH3)]

P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

A

(η5-C5H4Me)Fe(CO)P(p-C6H4OMe)3I

(η5-C5H4Me)Fe(CO)P(p-C6H4OMe)3I

B

[(η5-C5H4Me)Fe(CO)2P(p-C6H4OMe)3]I
959421-09-1

[(η5-C5H4Me)Fe(CO)2P(p-C6H4OMe)3]I

Conditions
ConditionsYield
di(cyclopentadienideiron dicarbonyl) In neat (no solvent) Fe-compound and P-compound placed in 1:5 molar ratio in agate mortar; gently ground; transferred into NMR tube; placed at 100°C for 15 min; chilled in ice;A 0%
B 100%
In neat (no solvent) Fe-compound and P-compound placed in 1:5 molar ratio in agate mortar; gently ground; transferred into NMR tube; placed at 70°C for 0.5 or4 min; chilled in ice;A 0%
B 100%
di(cyclopentadienideiron dicarbonyl) In neat (no solvent) Fe-compound and P-compound placed in 1:5 molar ratio in agate mortar; gently ground; transferred into NMR tube; placed at 100°C for 5 min; chilled in ice;A 0%
B 84%
P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

tris(4-methoxyphenyl)phosphonium tetrafluoroborate

tris(4-methoxyphenyl)phosphonium tetrafluoroborate

Conditions
ConditionsYield
With tetrafluoroboric acid In diethyl ether at 20℃; Inert atmosphere;100%
(tetrahydrothiophene)gold(I) chloride
39929-21-0

(tetrahydrothiophene)gold(I) chloride

P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

(tris(4-methoxyphenyl)phosphine)gold(I) chloride
96029-36-6

(tris(4-methoxyphenyl)phosphine)gold(I) chloride

Conditions
ConditionsYield
In dichloromethane at 20℃; for 15h; Inert atmosphere;100%
In dichloromethane at 20℃; for 1h;63%
In not given addn. of P compd. to Au complex;
P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

7-azido-4-methyl-2H-chromen-2-one

7-azido-4-methyl-2H-chromen-2-one

4-methyl-7-((tris(4-methoxyphenyl)-λ5-phosphanylidene)-amino)-2H-chromen-2-one

4-methyl-7-((tris(4-methoxyphenyl)-λ5-phosphanylidene)-amino)-2H-chromen-2-one

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 1h; Inert atmosphere;100%
P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

α,α'-dibromo-o-xylene
91-13-4

α,α'-dibromo-o-xylene

(2-(bromomethyl)benzyl)tris(4-methoxyphenyl)phosphonium bromide

(2-(bromomethyl)benzyl)tris(4-methoxyphenyl)phosphonium bromide

Conditions
ConditionsYield
In toluene at 20℃; Inert atmosphere; Schlenk technique;99.5%
chloro(1,5-cyclooctadiene)rhodium(I) dimer

chloro(1,5-cyclooctadiene)rhodium(I) dimer

P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

1-adamantyl isocyanide
22110-53-8

1-adamantyl isocyanide

C53H57ClNO6P2Rh

C53H57ClNO6P2Rh

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 1h;99%
P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

trimethoxonium tetrafluoroborate
420-37-1

trimethoxonium tetrafluoroborate

C22H24O3P(1+)*BF4(1-)

C22H24O3P(1+)*BF4(1-)

Conditions
ConditionsYield
In dichloromethane at 20℃; for 3h; Inert atmosphere;99%
P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

methyl 4-azidotetrafluorobenzoate
122590-75-4

methyl 4-azidotetrafluorobenzoate

methyl 2,3,5,6-tetrafluoro-4-((tris(4-methoxyphenyl)-λ5-phosphanylidene)amino)benzoate

methyl 2,3,5,6-tetrafluoro-4-((tris(4-methoxyphenyl)-λ5-phosphanylidene)amino)benzoate

Conditions
ConditionsYield
at 25℃; for 2h; Kinetics; Inert atmosphere;99%
P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

PtCl(8-O-quinoline)(dmso)

PtCl(8-O-quinoline)(dmso)

C51H48NO7P2Pt(1+)*Cl(1-)

C51H48NO7P2Pt(1+)*Cl(1-)

Conditions
ConditionsYield
In chloroform at 60℃; for 24h; Schlenk technique; Inert atmosphere;99%
P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

3-hydroxy-4-iodopyridine
188057-20-7

3-hydroxy-4-iodopyridine

(3-hydroxypyridin-4-yl)tris(4-methoxyphenyl)phosphonium iodide

(3-hydroxypyridin-4-yl)tris(4-methoxyphenyl)phosphonium iodide

Conditions
ConditionsYield
In chloroform at 50℃; for 19h;99%
P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

4-iodo-3,5-dimethylpyridine

4-iodo-3,5-dimethylpyridine

(3,5-dimethylpyridin-4-yl)tris(4-methoxyphenyl)phosphonium iodide

(3,5-dimethylpyridin-4-yl)tris(4-methoxyphenyl)phosphonium iodide

Conditions
ConditionsYield
In chloroform at 80℃; for 19h;99%
P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

5-bromo-2-chloro-4-iodopyridine
401892-47-5

5-bromo-2-chloro-4-iodopyridine

(5-bromo-2-chloropyridin-4-yl)tris(4-methoxyphenyl)phosphonium iodide

(5-bromo-2-chloropyridin-4-yl)tris(4-methoxyphenyl)phosphonium iodide

Conditions
ConditionsYield
In chloroform at 80℃; for 19h;99%
P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

3-(allyloxy)-4-iodopyridine

3-(allyloxy)-4-iodopyridine

I(1-)*C29H29NO4P(1+)

I(1-)*C29H29NO4P(1+)

Conditions
ConditionsYield
In chloroform at 20℃; for 36h;99%
(1,2,5,6-η4-cycloocta-1,5-diene)bis(4-methoxyphenyl)platinum(II)

(1,2,5,6-η4-cycloocta-1,5-diene)bis(4-methoxyphenyl)platinum(II)

P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

cis-bis(4-methoxyphenyl)bis{tris(4-methoxyphenyl)phosphane}platinum(II)

cis-bis(4-methoxyphenyl)bis{tris(4-methoxyphenyl)phosphane}platinum(II)

Conditions
ConditionsYield
In dichloromethane dropping of soln. of phosphane derivative to soln. of Pt complex then stirring at 0°C for 6 h; evapg. of solvent, hydrolysing with ice water, sepg., extg. of aq. layer with C6H6 then CH2Cl2, washing with H2O, drying over MgSO4, evapg. to dryness, dissolving in CH2Cl2 then pptg. with n-hexane; elem. anal.;98%
allyl(cyclopentadiene)palladium(II)
1271-03-0

allyl(cyclopentadiene)palladium(II)

4-fluoro-1-iodobenzene
352-34-1

4-fluoro-1-iodobenzene

P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

(4-fluorophenyl)Pd(P(4-methoxyphenyl)3)2I
180891-50-3

(4-fluorophenyl)Pd(P(4-methoxyphenyl)3)2I

Conditions
ConditionsYield
In dichloromethane Ar-atmosphere; stirring (room temp., 5 - 15 min); filtering (PTFE membrane), crystn. on concg. and hexane addn. (-30°C, overnight), filtering, drying (vac.); elem. anal.;98%
(η5-cyclopentadienyl)(p-toluenesulfonylimido-kN-thio-kS-ethene-2-thiolato-kS)cobalt(III)

(η5-cyclopentadienyl)(p-toluenesulfonylimido-kN-thio-kS-ethene-2-thiolato-kS)cobalt(III)

P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

C5H5CoS2C2(COOCH3)2NSO2C6H4CH3P(C6H4OCH3)3

C5H5CoS2C2(COOCH3)2NSO2C6H4CH3P(C6H4OCH3)3

Conditions
ConditionsYield
In dichloromethane (Ar); stirring a soln. of cobalt complex and phosphine in CH2Cl2 at roomtemp. for 5 min; evapn., column chromy.;98%
3-Bromopropionic acid
590-92-1

3-Bromopropionic acid

P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

C24H26O5P(1+)*Br(1-)
1394132-29-6

C24H26O5P(1+)*Br(1-)

Conditions
ConditionsYield
In toluene for 5h; Reflux;98%
thallium(I) hexafluorophosphate

thallium(I) hexafluorophosphate

(tris(4-methoxyphenyl)phosphine)gold(I) chloride
96029-36-6

(tris(4-methoxyphenyl)phosphine)gold(I) chloride

P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

[Au{tris((4-methoxyphenyl)phosphine)2}]PF6

[Au{tris((4-methoxyphenyl)phosphine)2}]PF6

Conditions
ConditionsYield
In dichloromethane for 1h; Darkness;98%
3-chloro-4 iodopyridine
77332-79-7

3-chloro-4 iodopyridine

P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

(3-chloropyridin-4-yl)tris(4-methoxyphenyl)phosphonium iodide

(3-chloropyridin-4-yl)tris(4-methoxyphenyl)phosphonium iodide

Conditions
ConditionsYield
In chloroform at 20℃; for 36h;98%
4-iodopyridin-2-ol

4-iodopyridin-2-ol

P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

tris(4-methoxyphenyl)(2-oxo-1,2-dihydropyridin-4-yl)phosphonium iodide

tris(4-methoxyphenyl)(2-oxo-1,2-dihydropyridin-4-yl)phosphonium iodide

Conditions
ConditionsYield
In chloroform at 50℃; for 19h;98%
copper(l) iodide
7681-65-4

copper(l) iodide

P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

2-(bis(4-methylphenyl)phosphino)-4-methylpyridine

2-(bis(4-methylphenyl)phosphino)-4-methylpyridine

(2-(bis(4-methylphenyl)phosphino)-4-methylpyridin)(tris(4-methoxyphenyl)phosphine)2Cu2I2

(2-(bis(4-methylphenyl)phosphino)-4-methylpyridin)(tris(4-methoxyphenyl)phosphine)2Cu2I2

Conditions
ConditionsYield
In dichloromethane at 25℃; for 15h; Inert atmosphere;98%
allyl(cyclopentadiene)palladium(II)
1271-03-0

allyl(cyclopentadiene)palladium(II)

4-tolyl iodide
624-31-7

4-tolyl iodide

P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

(4-methylphenyl)Pd(P(4-methoxyphenyl)3)2I
180891-49-0

(4-methylphenyl)Pd(P(4-methoxyphenyl)3)2I

Conditions
ConditionsYield
In dichloromethane Ar-atmosphere; stirring (room temp., 5 - 15 min); filtering (PTFE membrane), crystn. on concg. and hexane addn. (-30°C, overnight), filtering, drying (vac.); elem. anal.;97%
{2-(dimethylaminomethyl)phenyl}(1,10-phenanthroline)gold(III) bis(tetrafluoroborate)

{2-(dimethylaminomethyl)phenyl}(1,10-phenanthroline)gold(III) bis(tetrafluoroborate)

P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

{Au((CH3)2NCH2C6H4)(C12H8N2)P(C6H4OCH3)3}(2+)*2{BF4}(1-) = {Au((CH3)2NCH2C6H4)(C12H8N2)P(C6H4OCH3)3}{BF4}2

{Au((CH3)2NCH2C6H4)(C12H8N2)P(C6H4OCH3)3}(2+)*2{BF4}(1-) = {Au((CH3)2NCH2C6H4)(C12H8N2)P(C6H4OCH3)3}{BF4}2

Conditions
ConditionsYield
In dichloromethane solid P(C6H4OMe-p)3 added at room temp.to a suspn. of Au-complex, stirred for 1 h; concd., Et2O added, filtered off, recrystd. from CH2Cl2-Et2O; elem. anal.;96%
pentacarbonyl[3-(dimethylamino)-3-phenyl-1,2-propadienylidene]chromium

pentacarbonyl[3-(dimethylamino)-3-phenyl-1,2-propadienylidene]chromium

P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

cis-tetracarbonyl(3-dimethylamino-3-phenylpropa-1,2-dienylidene)[tris(4-methoxyphenyl)phosphane]chromium

cis-tetracarbonyl(3-dimethylamino-3-phenylpropa-1,2-dienylidene)[tris(4-methoxyphenyl)phosphane]chromium

Conditions
ConditionsYield
In tetrahydrofuran byproducts: CO; Irradiation (UV/VIS); (Ar); irradn. of a soln. of chromium complex and phosphine in THF at -20°C for 2.5 h; evapn., chromy. (silica gel, pentane/CH2Cl2/THF); elem. anal.;96%
ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

dichloromethane
75-09-2

dichloromethane

(OC)3Fe((CH2)3S2)Ni(Ph2P(CH2)2PPh2)
877034-21-4, 877034-22-5

(OC)3Fe((CH2)3S2)Ni(Ph2P(CH2)2PPh2)

P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

[(dppe)Ni(propaneditiolate)Fe(CO)2(P(p-C6H4OMe)3)]BF4*0.25CH2Cl2

[(dppe)Ni(propaneditiolate)Fe(CO)2(P(p-C6H4OMe)3)]BF4*0.25CH2Cl2

Conditions
ConditionsYield
With pentane In dichloromethane MBraun glovebox, under N2; soln. of NiFe compd. and FcBF4 in CH2Cl2, rapid stirring for 1 min, above soln. added to phosphine in CH2Cl2, 0.5 min, pentane added (-28°C, then 1 h at this temp.); filtered, washed (pentane, -28°C), dried; elem. anal.;96%
dicarbonyl(chloro)(η5-pentaphenylcyclopentadienyl)ruthenium(II)
677736-23-1

dicarbonyl(chloro)(η5-pentaphenylcyclopentadienyl)ruthenium(II)

P(p-CH3OC6H4)3
855-38-9

P(p-CH3OC6H4)3

carbonyl(chloro)(tris(4-methoxyphenyl)phosphine-κP)(η5-pentaphenylcyclopentadienyl)ruthenium(II)

carbonyl(chloro)(tris(4-methoxyphenyl)phosphine-κP)(η5-pentaphenylcyclopentadienyl)ruthenium(II)

Conditions
ConditionsYield
With trimethylamine-N-oxide In dichloromethane; acetonitrile at 20℃; for 2h; Inert atmosphere; Schlenk technique;96%

855-38-9Relevant articles and documents

Photochemical transformation of chlorobenzenes and white phosphorus into arylphosphines and phosphonium salts

Gschwind, Ruth M.,Mende, Michael,Scott, Daniel J.,Streitferdt, Verena,Till, Marion,Wolf, Robert

supporting information, p. 1100 - 1103 (2022/02/03)

Chlorobenzenes are important starting materials for the preparation of commercially valuable triarylphosphines and tetraarylphosphonium salts, but their use for the direct arylation of elemental phosphorus has been elusive. Here we describe a simple photochemical route toward such products. UV-LED irradiation (365 nm) of chlorobenzenes, white phosphorus (P4) and the organic superphotoreductant tetrakis(dimethylamino)ethylene (TDAE) affords the desired arylphosphorus compounds in a single reaction step.

A Lewis Base Nucleofugality Parameter, NFB, and Its Application in an Analysis of MIDA-Boronate Hydrolysis Kinetics

García-Domínguez, Andrés,Gonzalez, Jorge A.,Leach, Andrew G.,Lloyd-Jones, Guy C.,Nichol, Gary S.,Taylor, Nicholas P.

supporting information, (2022/01/04)

The kinetics of quinuclidine displacement of BH3 from a wide range of Lewis base borane adducts have been measured. Parameterization of these rates has enabled the development of a nucleofugality scale (NFB), shown to quantify and predict the leaving group ability of a range of other Lewis bases. Additivity observed across a number of series R′3-nRnX (X = P, N; R′ = aryl, alkyl) has allowed the formulation of related substituent parameters (nfPB, nfAB), providing a means of calculating NFB values for a range of Lewis bases that extends far beyond those experimentally derived. The utility of the nucleofugality parameter is explored by the correlation of the substituent parameter nfPB with the hydrolyses rates of a series of alkyl and aryl MIDA boronates under neutral conditions. This has allowed the identification of MIDA boronates with heteroatoms proximal to the reacting center, showing unusual kinetic lability or stability to hydrolysis.

The Trityl-Cation Mediated Phosphine Oxides Reduction

Landais, Yannick,Laye, Claire,Lusseau, Jonathan,Robert, Frédéric

supporting information, p. 3035 - 3043 (2021/05/10)

Reduction of phosphine oxides into the corresponding phosphines using PhSiH3 as a reducing agent and Ph3C+[B(C6F5)4]? as an initiator is described. The process is highly efficient, reducing a broad range of secondary and tertiary alkyl and arylphosphines, bearing various functional groups in generally good yields. The reaction is believed to proceed through the generation of a silyl cation, which reaction with the phosphine oxide provides a phosphonium salt, further reduced by the silane to afford the desired phosphine along with siloxanes. (Figure presented.).

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