Photocatalytic Synthesis of γ-Lactones from Alkenes: High-Resolution Mass Spectrometry as a Tool to Study Photoredox Reactions

DOI: 10.1021/acs.orglett.7b03256

Source and publish data:

Organic Letters p. 36 - 39 (2018)

Update date:2022-09-26

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Authors:

Triandafillidi, Ierasia

Kokotou, Maroula G.

Kokotos, Christoforos G.

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Article abstract of DOI:10.1021/acs.orglett.7b03256

A mild photocatalytic manifold for the synthesis of γ-lactones has been developed. Utilizing Ru(bpy)₃Cl₂ as the photocatalyst, a cheap and reproducible synthetic protocol for γ-lactones has been introduced. Mechanistic studies revealed the successful monitoring of photocatalytic reactions and radical intermediates via high-resolution mass spectrometry.

Full text of DOI:10.1021/acs.orglett.7b03256

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