Chemistry Letters p. 639 - 642 (1985)
Update date:2022-08-03
Topics:
Hatsui, Toshihide
Suzuki, Nobumasa
Takeshita, Hitoshi
9,10-Dicyanoanthracene-sensitized photooxygenation of thujopsene proceeded by singlet oxygen, but the reaction with added biphenyl caused an electron transfer and produced a novel product which has no longer possessed the cyclopropane ring.The ring cleavage is best explained in terms of intermediary formation of a radical cation.
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