A FACILE SYNTHESIS OF HOMOALLYL ETHERS. THE REACTION OF ACETALS WITH ALLYLTRIMETHYLSILANES PROMOTED BY TRITYL PERCHLORATE OR DIPHENYLBORYL TRIFLATE

DOI: 10.1246/cl.1985.977

Source and publish data:

Chemistry Letters p. 977 - 980 (1985)

Update date:2022-09-26

Topics:

Authors:

Mukaiyama, Teruaki

Nagaoka, Hitoshi

Murakami, Masahiro

Ohshima, Masahiro

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Article abstract of DOI:10.1246/cl.1985.977

In the presence of a catalytic amount of trityl perchlorate or diphenylboryl triflate, acetals react smoothly with allyltrimethylsilanes to give the corresponding homoallyl ethers in good yields with good regio- and stereoselectivities.

Full text of DOI:10.1246/cl.1985.977

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