Carbopalladation of Β-allenylmalonates: a way to cyclopentenyl or vinylcyclopropyl derivatives.

DOI: 10.1016/S0040-4039(00)89253-9

Source and publish data:

Tetrahedron Letters p. 3795 - 3798 (1985)

Update date:2022-07-29

Topics:

Authors:

Ahmar, Mohammed

Cazes, Bernard

Gore, Jacques

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Article abstract of DOI:10.1016/S0040-4039(00)89253-9

The palladium-catalyzed addition of a vinyl or aryl halide to the enolate of Β-allenyl malonate 2 leads to the formation of either of the two cyclized products 3 and 4 depending mainly on the bulk of the starting unsaturated halide.

Full text of DOI:10.1016/S0040-4039(00)89253-9

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