Tetrahedron p. 77 - 90 (1989)
Update date:2022-07-29
Topics: Free radical Novel Reaction Experimental Ring-expansion
Dowd, Paul
Choi, Soo-Chang
A novel free radical initiated ring expansion of haloalkyl β-keto esters is described.Following alkylation of the β-keto ester with the appropriate dihalide, the resulting halide is treated at reflux with tri-n-butyltin hydride.Rearrangement to the homolo
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