REGULATION PAR LES IONS POTASSIUM DE LA FORMATION D'UN COMPLEXE INTERMOLECULAIRE DE TRANSFERT DE CHARGE Un modele simple de l'effet allosterique

DOI: 10.1016/S0040-4039(00)82486-7

Source and publish data:

Tetrahedron Letters p. 933 - 936 (1988)

Update date:2022-07-30

Topics:

Authors:

Gagnaire, Genevieve

Gellon, Gisele

Pierre, Jean-Louis

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Article abstract of DOI:10.1016/S0040-4039(00)82486-7

A noncyclic glycol ether type ligand, carrying two terminal electron-donor groups shows intermolecular charge transfer interaction with TCNQ.The thermodynamic equilibrium constant is strongly influenced by addition of potassium perchlorate.The results are discussed in view of steric effects which mimics allosteric effects.

Full text of DOI:10.1016/S0040-4039(00)82486-7

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