Stereoselective Total Synthesis of (+/-)-Isocelorbicol

DOI: 10.1021/jo00361a049

Source and publish data:

Journal of Organic Chemistry p. 2148 - 2150 (1986)

Update date:2022-08-03

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Authors:

Huffman, John W.

Raveendranath, Panolil C.

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Article abstract of DOI:10.1021/jo00361a049

The naturally occurring trihydroxyagarofuran (+/-)-isocelorbicol (1) has been synthesized in 15 steps (3.2percent) from 9-keto-α-agarofuran (2).This completely stereoselective synthesis includes an osmium tetraoxide oxidation in which the reagent attacks

Full text of DOI:10.1021/jo00361a049

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