
Journal of Organic Chemistry p. 2148 - 2150 (1986)
Update date:2022-08-03
Topics:
Huffman, John W.
Raveendranath, Panolil C.
The naturally occurring trihydroxyagarofuran (+/-)-isocelorbicol (1) has been synthesized in 15 steps (3.2percent) from 9-keto-α-agarofuran (2).This completely stereoselective synthesis includes an osmium tetraoxide oxidation in which the reagent attacks
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