SYNTHESIS OF Β,Γ-UNSATURATED CARBOXYLIC ACID DERIVATIVES BY THE NOVEL Ni(CO)4-INDUCED RING-OPENING CARBONYLATION REACTION OF 1,1-DIBROMO-2-CHLOROCYCLOPROPANES

DOI: 10.1246/cl.1985.1625

Source and publish data:

Chemistry Letters p. 1625 - 1628 (1985)

Update date:2022-07-30

Topics:

Authors:

Hirao, Toshikazu

Nagata, Shinichiro

Agawa, Toshio

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Article abstract of DOI:10.1246/cl.1985.1625

1,1-Dibromo-2-chlorocyclopropanes underwent the Ni(CO)4-induced ring-opening carbonylation reaction with alcohol or amine giving the β,γ-unsaturated carboxylic acid and dicarboxylic acid derivatives.Use of N,N-dimethyltrimethylsilylamine as an initial nuc

Full text of DOI:10.1246/cl.1985.1625

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