
Journal of Organic Chemistry p. 2767 - 2770 (1986)
Update date:2022-08-04
Topics:
Hassner, Alfred
Keogh, Joseph
Iodine azide was found to undergo monoaddition to alkyl-substituted allenes 8-11, producing regioselectively allyl azides that can undergo <3,3>rearrangement.Allene itself ia an exception and adds IN3 at room temperature to form a bisadduct, shown to have
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(1957)