Tetrahedron p. 5205 - 5208 (1985)
Update date:2022-09-26
Topics:
Sydnes, Leiv K.
Hansen, Sissel H.
Burkow, Ivan C.
Saethre, Leif J.
When 1,2-,1,3-and 1,6-dimethylnaphthalene are oxidized by Ce(4+) in acetic acid the corresponding monoaldehydes are formed in better than 80percent yield.In each case aldehyde formation takes place with a high degree of selectivity as the methyl-1-to methyl-2-naphthaldehyde ratio is better than 11:1.The selectivity may be explained from differences in reactivity as calculated within the frontier orbital method.
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