Journal of Organic Chemistry p. 2857 - 2858 (1986)
Update date:2022-07-30
Topics:
Padwa, Albert
Gasdaska, John R.
The <2,3>-sigmatropic rearrangement of sulfur ylides derived via the desilylation of several α-trimethylsilyl benzylsulfonium salts has been studied.The initially formed ylide was found to rapidly equilibrate with the thermodynamically more stable ylide.In the absence of trapping reagents, a Sommelet-Hauser-type rearrangement occurs.
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