FeCl3·6H2O, a catalyst for the diastereoselective synthesis of cis-isoxazolidines from N-protected δ-hydroxylamino allylic acetates

DOI: 10.1021/jo401627p

Source and publish data:

Journal of Organic Chemistry p. 10273 - 10287 (2013)

Update date:2022-08-03

Topics: Synthesis Catalyst Diastereoselective Allylic Acetates N-Protected

Authors:

Cornil, Johan

Guerinot, Amandine

Reymond, Sebastien

Cossy, Janine

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Article abstract of DOI:10.1021/jo401627p

An ecofriendly and diastereoselective synthesis of cis-3,5-disubstituted isoxazolidines through the FeCl₃·6H₂O-catalyzed cyclization of δ-hydroxylamino allylic acetates is described. The synthetic potential of these products is highlighted by the preparation of several functionalized 1,3-amino alcohol precursors.

Full text of DOI:10.1021/jo401627p

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