Tetrahedron Letters p. 731 - 734 (1999)
Update date:2022-07-30
Topics:
Mori, Yuji
Sawada, Tomoko
Furukawa, Hiroshi
The stereocontrolled synthesis of (6S,7S,9R,10R)-6,9-epoxynonadec-18- ene-7,10-diol, isolated from the brown alga, Notheia anomala, has been achieved. The key 2,3,5-trisubstituted tetrahydrofuran ring was constructed by alkylation of the sulfonyl-stabilized oxiranly anion followed by 5-endo cyclization.
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