BIOSYNTHETIC STUDIES OF MARINE LIPIDS 8. COURSE OF THE STEREOSELECTIVE ALKYLATION AND REGIOSELECTIVE HYDROGEN MIGRATION IN THE BIOSYNTHESIS OF THE SPONGE STEROL 24(S)-24-ISOPROPENYLCHOLESTEROL

DOI: 10.1016/S0040-4020(01)87638-9

Source and publish data:

Tetrahedron p. 4156 - 4160 (1986)

Update date:2022-07-30

Topics:

Authors:

Stoilov, Ivan

Back, Thomas G.

Thompson, Janice E.

Djerassi, Carl

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)87638-9

The detailed mechanism of the formation of (24S)-24-isopropenylcholesterol, the key intermediate in the biosynthesis of 24-isopropylcholesterol, was studied in a Pseudoaxinyssa sponge species.A stereoselective alkylation at C28 of (iso)fucosterol was demo

Full text of DOI:10.1016/S0040-4020(01)87638-9

Products guided by the article

Product name:Toluene-4-sulfonic acid (R)-6-((1aS,3aR,3bS,5aR,6R,8aS,8bS,10R,10aR)-10-methoxy-3a,5a-dimethyl-hexadecahydro-cyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalen-6-yl)-2-methyl-3-methylene-heptyl ester

Cas No:104959-02-6

R&D Labs maybe for 104959-02-6

Qingdao S. H. Huanyu Imp. & Exp. Co., Ltd.

Contact:86-532-88250866

Address:Room 615, World Trade Centre Building B, Hongkong Middle Roda 6#, Qingdao, Shandong, China
WEIFANG RICHEM INTERNATIONAL LTD

Contact:86-536-2222176

Address:weifang,shandong
Chemsigma International Co.,Ltd.

website:http://www.chemsigma.com

Contact:86-025-58748998

Address:Rm.705, 15th Building,Rd.Xinke II
Chengdu Chengnuo New-Tech Co., Ltd

Contact:0086-028-85749078

Address:4 Jiuyang road,Jiulong industrial port,Chengdu, China
Jiaxing Anrui Material Technology Co., Ltd.

Contact:86-573-82651652 13305832579

Address:Room 407, Technology Building, 1369 Chennan Road, Jiaxing City, Zhejiang, China

Relevant to this article

A mild protocol for the efficient synthesis of 5,6-unsubstituted 1,4-dihydropyridines

Doi:10.1055/s-0029-1217719
(2009)
The Chemistry of Rhenium and Tungsten Porphyrin Complexes in Low Oxidation States. Synthesis and Characterization of Rhenium and Tungsten Porphyrin Dimers Containing Metal-Metal Multiple Bonds

Doi:10.1021/ja00203a013
(1989)
Syntheses of quaternary carbon-containing oxazatricycle and spiropyran libraries via multicomponent reactions and their molecular switching properties

Doi:10.1021/cc900127g
(2010)
Practical Peptide Synthesis Mediated by a Recyclable Hypervalent Iodine Reagent and Tris(4-methoxyphenyl)phosphine

Doi:10.1021/acs.orglett.5b02045
(2015)
Asymmetric Michael addition reaction of 3-substituted oxindoles to nitroolefins catalyzed by a chiral alkyl-substituted thiourea catalyst

Doi:10.1002/adsc.200900630
(2010)
Novel synthesis of 2,4-bis(2-pyridyl)-5-(pyridyl)imidazoles and formation of N-(3-(pyridyl)imidazo[1,5-a]pyridine)picolinamidines: nitrogen-rich ligands

Doi:10.1016/j.tetlet.2009.09.002
(2009)

Article Doi