BIOSYNTHETIC STUDIES OF MARINE LIPIDS 8. COURSE OF THE STEREOSELECTIVE ALKYLATION AND REGIOSELECTIVE HYDROGEN MIGRATION IN THE BIOSYNTHESIS OF THE SPONGE STEROL 24(S)-24-ISOPROPENYLCHOLESTEROL

DOI: 10.1016/S0040-4020(01)87638-9

Source and publish data:

Tetrahedron p. 4156 - 4160 (1986)

Update date:2022-07-30

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Authors:

Stoilov, Ivan

Back, Thomas G.

Thompson, Janice E.

Djerassi, Carl

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Article abstract of DOI:10.1016/S0040-4020(01)87638-9

The detailed mechanism of the formation of (24S)-24-isopropenylcholesterol, the key intermediate in the biosynthesis of 24-isopropylcholesterol, was studied in a Pseudoaxinyssa sponge species.A stereoselective alkylation at C28 of (iso)fucosterol was demo

Full text of DOI:10.1016/S0040-4020(01)87638-9

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