Nonbonded Interactions between Proximate Phenyl and Polyfluorophenyl Rings. Reactivity in Polyfluorocyclophanes

DOI: 10.1021/jo00380a006

Source and publish data:

Journal of Organic Chemistry p. 511 - 515 (1987)

Update date:2022-07-30

Topics:

Authors:

Filler, Robert

Cantrell, Gary L.

Choe, Eui W.

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Article abstract of DOI:10.1021/jo00380a006

The replacement of a phenyl ring tetrafluorophenyl in <2.2>paracyclophane causes a remarkable deactivation of the other phenyl ring toward electrophilic substitution (acetylation, bromination) and acid-catalyzed rearrangement to the <2.2>metaparacyclophan

Full text of DOI:10.1021/jo00380a006

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