Tetrahedron p. 2657 - 2666 (1986)
Update date:2022-08-05
Topics:
Lamaty, G.
Roque, J. P.
Natat, A.
Silou, T.
The equilibrium constants of formation, K1, of carbinolamines resulting from the addition of hydroxylamine to 19 ketones, - 5 aliphatic, 5 aromatic and 9 cyclanic -, have been measured at 25 deg C in water/methanol 60/40 v/v.A general method of determination of K1 is described.The variations of equilibrium constant are discussed in terms of torsional and nonbonding steric effects which are the main factors of reactivity for saturated ketones.
View Morewebsite:http://www.orchid-chem.com
Contact:+86-571-85395792
Address:607, North Zhongshan Road, Hangzhou 310000 China
website:http://www.weichichem.com
Contact:+8613912949432
Address:Fine Chemical Industrial Base,Wujiang town,He County,Anhui China.
Anhui Jiatiansen Agrochemical Co.,Ltd
Contact:15366811918
Address:chemical industrial park,xiangyu town,dongzhi county,anhui,china
Chengdu ZY Biochemical Technology Co., LTD
Contact:0086-28-88680086
Address:170 Qingpu Road, Shouan Town, Pujiang County
Nanjing Fubang Chemical Co.,Ltd
Contact:+86-25-83179199
Address:5F,Tianzheng international plaza,No399 Zhongyang Road ,Nanjing China
Doi:10.1016/S0040-4020(01)87588-8
(1986)Doi:10.1016/j.carres.2008.06.028
(2008)Doi:10.1021/ol801830h
(2008)Doi:10.1039/DT9860001411
(1986)Doi:10.1021/ol802005n
(2008)Doi:10.1021/ja016121w
(2001)
