UEBERGANGSMETALL-SILYL-KOMPLEXE VI. CH3/Cl-AUSTAUSCH BEI DER REAKTION VON R3P-Au-CH3 MIT CHLORSILANEN

DOI: 10.1016/0022-328X(86)80121-8

Source and publish data:

Journal of Organometallic Chemistry p. C5 - C7 (1986)

Update date:2022-08-02

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Authors:

Schubert, Ulrich

Meyer, Juergen

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Article abstract of DOI:10.1016/0022-328X(86)80121-8

The reaction of R3P-Au-CH3 (R3P = TolPh2P or Me2PhP) with organosilicon halides HSiR2Cl (HSiPh2Cl, HSiMeCl2, HSiMe2Cl) yields R3P-Au-Cl and the corresponding methylated silanes HSiR2CH3 by CH3/Cl exchange.Oxidative addition of the Si-H group of several H-

Full text of DOI:10.1016/0022-328X(86)80121-8

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