UEBERGANGSMETALL-SILYL-KOMPLEXE VI. CH3/Cl-AUSTAUSCH BEI DER REAKTION VON R3P-Au-CH3 MIT CHLORSILANEN

Article abstract of DOI:10.1016/0022-328X(86)80121-8

The reaction of R3P-Au-CH3 (R3P = TolPh2P or Me2PhP) with organosilicon halides HSiR2Cl (HSiPh2Cl, HSiMeCl2, HSiMe2Cl) yields R3P-Au-Cl and the corresponding methylated silanes HSiR2CH3 by CH3/Cl exchange.Oxidative addition of the Si-H group of several H-