Journal of Organic Chemistry p. 2402 - 2404 (1986)
Update date:2022-07-30
Topics:
Davis, Franklin A.
Haque, M. Serajul
Ulatowski, Terrance G.
Towson, James C
The first asymmetric oxidation of ester and amide lithium enolates 5 to optically active α-hydroxycarbonyl compounds 6 is reported using new, easily prepared, stable (camphorylsulfonyl)oxaziridines (+)-(2R,8aS)-3 and (-)-(2S,8aR)-4.Either enantiomer of 6 can be readily obtained because the configuration of the oxaziridine three-membered ring determines the product stereochemistry.
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Doi:10.1039/b807810f
(2008)Doi:10.1016/S0022-1139(00)81949-1
(1986)Doi:10.1002/ejic.200700414
(2007)Doi:10.1016/j.tetlet.2006.02.028
(2006)Doi:10.1016/S0040-4020(01)87551-7
(1986)Doi:10.1007/BF03249088
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