A NEW ROUTE TO 3-HYDROXYPHTHALIDES : APPLICATION TO THE SYNTHESIS OF RACEMIC DAUNOMYCINONE.

DOI: 10.1016/S0040-4039(00)84815-7

Source and publish data:

Tetrahedron Letters p. 3431 - 3434 (1986)

Update date:2022-08-03

Topics:

Authors:

Becker, Anna M.

Irvine, Robert W.

McCormick, Alison S.

Russell, Richard A.

Warrener, Ronald N.

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Article abstract of DOI:10.1016/S0040-4039(00)84815-7

Lithiation (n-BuLi) of the (3'-methoxyphenyl) oxazoline (2a) occurs specifically at C2' and, following carboxylation (CO2/13CO2) and esterification, yields the phthalate derivative (e.g. 5a).Elaboration of the oxazoline-ring furnishes the related aldehyde

Full text of DOI:10.1016/S0040-4039(00)84815-7

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