
Chemistry Letters p. 1809 - 1812 (1986)
Update date:2022-08-03
Topics:
Yura, Takeshi
Iwasawa, Nobuharu
Clark, Richard
Mukaiyama, Teruaki
In the presence of chiral diamines, the reaction between tin(II) enolates of ketones or 3-acyl-2-oxazolidones and thiosulfonates proceeds smoothly to give the corresponding β-keto sulfides with high enetioselectivity.Further, optically active epoxides are prepared from these β-keto sulfides.
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Doi:10.1246/cl.1984.1153
(1984)Doi:10.1016/S0008-6215(00)90153-8
(1986)Doi:10.1021/ja993922e
(2000)Doi:10.1246/bcsj.60.4385
(1987)Doi:10.1039/a606311j
(1997)Doi:10.1016/S0040-4039(00)85292-2
(1986)