Journal of the Chemical Society. Chemical communications p. 22 - 23 (1984)
Update date:2022-08-03
Topics:
Baldwin, Jack E.
Bottaro, Jeffrey C.
Kolhe, Jayant N.
Adlington, Robert M.
The lithium salts for trityl- and diphenyl-4-pyridylmethyl-hydrazones of both aldehydes and ketones react with electrophiles (alkyl halides, aldehydes, and ketones) at low temperature to form C-trapped azo compounds; these intermediates decompose homolytically with loss of nitrogen below room temperature and can be diverted in a synthetically useful way to alkanes, or alkenes, or alcohols.
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