An Unusual Cyclization of a Homoallyl Oxyacetic Acid Dianion

DOI: 10.1021/jo00389a022

Source and publish data:

Journal of Organic Chemistry p. 2760 - 2762 (1987)

Update date:2022-08-05

Topics:

Authors:

Raucher, Stanley

Gustavson, Linda M.

Stencamp, Ronald E.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00389a022

Treatment of the homoallyl oxyacetic acid 7 with excess LDA at -78 deg C followed by thermolysis at 185 deg C in HMPA provided the unusual cyclization product 8a.A single-crystal X-ray structure was obtined for the derivative 8c.

Full text of DOI:10.1021/jo00389a022

Products guided by the article

Product name:(5R,6S)-2-methyl-5-(2-propenyl)-6-ethenyl-2-cyclohexenone

Cas No:108510-47-0

R&D Labs maybe for 108510-47-0

Qingdao Pana-Life Biochem Co.,Ltd.

Contact:86-532-87683902

Address:No.967 Dalao Road, Licang Zone, Qingdao City,Shandong, China 266021
Springchem New Material Technology Co.,Limited

website:http://www.spring-chem.com

Contact:86-21-62885108

Address:602B, Building 1, No. 641, Tianshan Road
Du-Hope International Group

website:http://www.np-chem.com

Contact:0086-25-52346877

Address:199, Jian Ye Road, Nanjing, China
Kaymossy BioChem Tech Co., Ltd

website:http://www.kaimosi.com

Contact:0571-87191913/0571-87199097

Address:Room 215, Building 3rd, No.288 Ningxia Road, Qingdao city, China
Shao Xing Empire Import&Export CO.,ltd

Contact:86-575-82127757

Address:11#, Weiwu Road, Shangyu Industrial Park, Hangzhou Bay, Hangzhou, Zhejiang Province, China

Relevant to this article

Synthesis, crystal structure and theoretical calculation of triphenyltin (IV) polymer based on 2,4-dichlorophenylacrylic acid

Doi:10.1080/24701556.2019.1703747
(2020)
SYNTHESIS OF (1,2,3,4,5/0)-5-HYDROXYMETHYL-1,2,3,4-CYCLOHEXANETETROL: PSEUDO-β-DL-TALOPYRANOSE

Doi:10.1016/S0008-6215(00)90192-7
(1986)
Doi:10.1021/jo01102a021
(1958)
Optimization and structure-activity relationship of a series of 1-phenyl-1,8-naphthyridin-4-one-3-carboxamides: Identification of MK-0873, a potent and effective PDE4 inhibitor

Doi:10.1016/j.bmcl.2008.09.009
(2008)
A novel one-step synthesis of symmetrical dialkyl trithiocarbonates in the presence of phase-transfer catalysis

Doi:10.1002/jccs.200800094
(2008)
Cyanophthalide annulation with 4-(5-alkoxy-2-furyl)-3-buten-2-one. Application to the synthesis of a (naphtho)pyrano-γ-lactone

Doi:10.1248/cpb.34.3175
(1986)

Article Doi