An Unusual Cyclization of a Homoallyl Oxyacetic Acid Dianion

DOI: 10.1021/jo00389a022

Source and publish data:

Journal of Organic Chemistry p. 2760 - 2762 (1987)

Update date:2022-08-05

Topics:

Authors:

Raucher, Stanley

Gustavson, Linda M.

Stencamp, Ronald E.

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Article abstract of DOI:10.1021/jo00389a022

Treatment of the homoallyl oxyacetic acid 7 with excess LDA at -78 deg C followed by thermolysis at 185 deg C in HMPA provided the unusual cyclization product 8a.A single-crystal X-ray structure was obtined for the derivative 8c.

Full text of DOI:10.1021/jo00389a022

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