Journal of Organic Chemistry p. 5288 - 5290 (1987)
Update date:2022-08-04
Topics:
Davis, Franklin A.
Ulatowski, Terrance G.
Haque, M. Serajul
Asymmetric oxidation of chiral acyclic, tetrasubstituted enolate 4c with oxaziridines (+)-1/(-)-2 in the presence and absence of HMPA affords optically active tertiary α-hydroxy amide 5c in high optical purity (88-91percent de).The application of (+)-1/(-)-2 as "chiral probes" of enolate-electrophile reaction mechanisms is proposed.
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