A Synthetic Entry into the Ophiobolane Ring System

DOI: 10.1021/jo00229a046

Source and publish data:

Journal of Organic Chemistry p. 4634 - 4635 (1987)

Update date:2022-07-29

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Authors:

Rigby, James H.

Senanayake, Chrisantha

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Article abstract of DOI:10.1021/jo00229a046

A stereocontrolled construction of the angularly fused 5-8-5 ring system characteristic of the ophiobolin and ceroplastol sesterterpenes is reported.The synthesis is based on the elaboration of a cis-hydroazulene intermediate into the dicyclopenta cyclooctane system with control of relative stereochemistry at several critical centers.

Full text of DOI:10.1021/jo00229a046

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