Tetrahedron p. 653 - 662 (1987)
Update date:2022-08-03
Topics:
Jackson, E. James
Misslitz, Ulf
Jones, Maitland
Meijere, A. de
Difluorocarbene reacts with 1,2,2-trimethylbicyclo<1.1.0>butane to give the product of two bond cleavage, 1,1-difluoro-3,3,4-trimethyl-1,4-pentadiene in 3percent yield.Bicyclo<2.1.0>pentane is even less reactive, yielding 1,1-difluorohexa-1,5-diene in ca. 0.5percent yield.Bicyclo<3.1.0>hexane does not react with difluorocarbene.Theoretical descriptions of these reactions are discussed.
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Doi:10.1021/jo00236a021
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