Preparation and Remarkable Reactivity of the Elusive (1,1,3,3-Tetramethylallyl)lithium

DOI: 10.1021/jo00039a031

Source and publish data:

Journal of Organic Chemistry p. 3680 - 3684 (1992)

Update date:2022-08-05

Topics:

Authors:

Cabral, Jose A.

Cohen, Theodore

Doubleday, Wendel W.

Duchelle, Ellen Francis

Fraenkel, Gideon

et al. et al.

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Article abstract of DOI:10.1021/jo00039a031

Although traditional methods of allyllithium production failed for (1,1,3,3-tetramethylallyl)lithium, it was readily prepared in a two-pot sequence starting with mesityl oxide.The key step is reductive lithiation of 4-(phenylthio)-2,4-dimethyl-2-pentene w

Full text of DOI:10.1021/jo00039a031

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