Chemistry Letters p. 455 - 458 (1987)
Update date:2022-08-03
Topics:
Matsubara, Yoshiharu
Takekuma, Shin-ichi
Yamamoto, Hiroshi
Nozoe, Tetsuo
Autoxidation of guaiazulene either at 85 deg C in N,N-dimethylformamide-0.5 M sulfuric acid or at 25-35 deg C on the surface of a filter paper yielded, together with other products, the two title compounds which were shown to be in equilibrium and to constitute important intermediates for the intermolecular one-carbon transfer reactions frequently observed during autoxidation of many azulenic hydrocarbons.
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