KINETICS OF REACTION OF TRIETHYLAMMONIUM CARBOXYLATES WITH α-HALOGENOCARBONYL COMPOUNDS IN ORGANIC SOLVENTS. REACTION OF BENZOATES AND PHENOXYACETATES WITH PHENACYL BROMIDE IN ACETONE

DOI: 10.1016/S0040-4020(01)90893-2

Source and publish data:

Tetrahedron p. 3899 - 3908 (1983)

Update date:2022-08-04

Topics:

Authors:

Pillay, M. Krishna

Kannan, K.

Ramasubramanian, P.

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Article abstract of DOI:10.1016/S0040-4020(01)90893-2

The kinetics of the reaction of phenacyl bromide with triethylammonium p-substituted benzoates and phenoxyacetates at 25 deg C, 30 deg C and 35 deg C in acetone suggest a rigid cyclic transition state involving a hydrogen bonded ion-pair as the active nuc

Full text of DOI:10.1016/S0040-4020(01)90893-2

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